Transient Sub-Band-Gap States at Grain Boundaries of CH3NH3PbI3 Perovskite Act as Fast Temperature Relaxation Centers

Xinyi Jiang, Justin Hoffman, Costas C. Stoumpos, Mercouri G Kanatzidis, Elad Harel

Research output: Contribution to journalArticle

Abstract

Extensive spectroscopic studies have been performed on grain boundaries (GBs) of thin-film metal halide perovskites, which inevitably form with current fabrication methods, but direct, on-site determination of the transition energy and dynamics of the associated defect states and their impact on local carrier behaviors have remained elusive. Here, scanning electron microscopy (SEM) correlated to transient absorption microscopy (TAM) on CH3NH3PbI3 perovskite particles is used to identify a defect state ∼60 meV into the band gap at GBs, which accelerates carrier cooling and act as additional energy acceptors. An in-depth statistical analysis performed on a large data set (806 distinct spatial locations) reveals that the shallow defect state, generally considered to be benign, plays a significant role in accelerating carrier cooling, which is detrimental to hot carrier solar cells.

Original languageEnglish
Pages (from-to)1741-1747
Number of pages7
JournalACS Energy Letters
Volume4
Issue number7
DOIs
Publication statusPublished - Jun 17 2019

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Perovskite
Grain boundaries
Energy gap
Defects
Cooling
Metal halides
Hot carriers
Temperature
Statistical methods
Solar cells
Microscopic examination
Fabrication
Thin films
Scanning electron microscopy
perovskite

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Transient Sub-Band-Gap States at Grain Boundaries of CH3NH3PbI3 Perovskite Act as Fast Temperature Relaxation Centers. / Jiang, Xinyi; Hoffman, Justin; Stoumpos, Costas C.; Kanatzidis, Mercouri G; Harel, Elad.

In: ACS Energy Letters, Vol. 4, No. 7, 17.06.2019, p. 1741-1747.

Research output: Contribution to journalArticle

Jiang, Xinyi ; Hoffman, Justin ; Stoumpos, Costas C. ; Kanatzidis, Mercouri G ; Harel, Elad. / Transient Sub-Band-Gap States at Grain Boundaries of CH3NH3PbI3 Perovskite Act as Fast Temperature Relaxation Centers. In: ACS Energy Letters. 2019 ; Vol. 4, No. 7. pp. 1741-1747.
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