Abstract
M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g-1). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.
| Original language | English |
|---|---|
| Pages (from-to) | 9376-9379 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue number | 67 |
| DOIs | |
| Publication status | Published - Jan 1 2017 |
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ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
Tuning ethylene gas adsorption via metal node modulation : Cu-MOF-74 for a high ethylene deliverable capacity. / Liao, Yijun; Zhang, Lin; Weston, Mitchell H.; Morris, William; Hupp, Joseph T; Farha, Omar K.
In: Chemical Communications, Vol. 53, No. 67, 01.01.2017, p. 9376-9379.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Tuning ethylene gas adsorption via metal node modulation
T2 - Cu-MOF-74 for a high ethylene deliverable capacity
AU - Liao, Yijun
AU - Zhang, Lin
AU - Weston, Mitchell H.
AU - Morris, William
AU - Hupp, Joseph T
AU - Farha, Omar K.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g-1). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.
AB - M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g-1). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.
UR - http://www.scopus.com/inward/record.url?scp=85027580271&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85027580271&partnerID=8YFLogxK
U2 - 10.1039/c7cc04160h
DO - 10.1039/c7cc04160h
M3 - Article
VL - 53
SP - 9376
EP - 9379
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 67
ER -