Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity

Yijun Liao; Lin Zhang; Mitchell H. Weston; William Morris; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c7cc04160h

Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity

Yijun Liao, Lin Zhang, Mitchell H. Weston, William Morris, Joseph T. Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g^-1). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.

Original language	English
Pages (from-to)	9376-9379
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	67
DOIs	https://doi.org/10.1039/c7cc04160h
Publication status	Published - Jan 1 2017

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Weston, Mitchell H.

AU - Morris, William

AU - Hupp, Joseph T.

AU - Farha, Omar K.

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