Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity

Yijun Liao; Lin Zhang; Mitchell H. Weston; William Morris; Joseph T Hupp; Omar K. Farha

doi:10.1039/c7cc04160h

Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity

Yijun Liao, Lin Zhang, Mitchell H. Weston, William Morris, Joseph T Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article

23 Citations (Scopus)

Abstract

M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g^-1). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.

Original language	English
Pages (from-to)	9376-9379
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	67
DOIs	https://doi.org/10.1039/c7cc04160h
Publication status	Published - Jan 1 2017

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Liao, Y., Zhang, L., Weston, M. H., Morris, W., Hupp, J. T., & Farha, O. K. (2017). Tuning ethylene gas adsorption via metal node modulation: Cu-MOF-74 for a high ethylene deliverable capacity. Chemical Communications, 53(67), 9376-9379. https://doi.org/10.1039/c7cc04160h

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Access to Document

10.1039/c7cc04160h