Tuning ethylene gas adsorption via metal node modulation

Cu-MOF-74 for a high ethylene deliverable capacity

Yijun Liao, Lin Zhang, Mitchell H. Weston, William Morris, Joseph T Hupp, Omar K. Farha

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

M-MOF-74s were examined for potential applications in ethylene abatement and/or storage/delivery. Due to labile binding resulting from a Jahn-Teller distortion, Cu-MOF-74 exhibits a gradual initial uptake that, in turn, translates into the highest deliverable capacity among the MOFs examined (3.6 mmol g-1). In contrast, Co-MOF-74 is the most promising candidate for ethylene abatement due to the sharp uptake at low pressure.

Original languageEnglish
Pages (from-to)9376-9379
Number of pages4
JournalChemical Communications
Volume53
Issue number67
DOIs
Publication statusPublished - Jan 1 2017

Fingerprint

Gas adsorption
Ethylene
Tuning
Metals
Modulation
Jahn-Teller effect
ethylene

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Tuning ethylene gas adsorption via metal node modulation : Cu-MOF-74 for a high ethylene deliverable capacity. / Liao, Yijun; Zhang, Lin; Weston, Mitchell H.; Morris, William; Hupp, Joseph T; Farha, Omar K.

In: Chemical Communications, Vol. 53, No. 67, 01.01.2017, p. 9376-9379.

Research output: Contribution to journalArticle

Liao, Yijun ; Zhang, Lin ; Weston, Mitchell H. ; Morris, William ; Hupp, Joseph T ; Farha, Omar K. / Tuning ethylene gas adsorption via metal node modulation : Cu-MOF-74 for a high ethylene deliverable capacity. In: Chemical Communications. 2017 ; Vol. 53, No. 67. pp. 9376-9379.
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