Tuning the Channel Size and Structure Flexibility of Metal-Organic Frameworks for the Selective Adsorption of Noble Gases

Liang Yu, Shunshun Xiong, Yuhan Lin, Liangying Li, Junjie Peng, Wei Liu, Xiaoxi Huang, Hao Wang, Jing Li

Research output: Contribution to journalArticle

Abstract

Two ultramicroporous metal-organic frameworks, Zn(ox)0.5(trz) and Zn(ox)0.5(atrz) (ox = oxalate, trz = triazolate, and atrz = 3-aminotriazolate), have been synthesized and tested for the adsorptive separation of Xe and Kr. We demonstrate that the Xe/Kr adsorption selectivity relates to the pore size as well as the structure flexibility of the adsorbents.

Original languageEnglish
JournalInorganic Chemistry
DOIs
Publication statusAccepted/In press - Jan 1 2019

Fingerprint

Noble Gases
Oxalates
oxalates
adsorbents
Adsorbents
Pore size
rare gases
flexibility
Tuning
selectivity
Metals
tuning
porosity
Adsorption
adsorption
metals

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Tuning the Channel Size and Structure Flexibility of Metal-Organic Frameworks for the Selective Adsorption of Noble Gases. / Yu, Liang; Xiong, Shunshun; Lin, Yuhan; Li, Liangying; Peng, Junjie; Liu, Wei; Huang, Xiaoxi; Wang, Hao; Li, Jing.

In: Inorganic Chemistry, 01.01.2019.

Research output: Contribution to journalArticle

Yu, Liang ; Xiong, Shunshun ; Lin, Yuhan ; Li, Liangying ; Peng, Junjie ; Liu, Wei ; Huang, Xiaoxi ; Wang, Hao ; Li, Jing. / Tuning the Channel Size and Structure Flexibility of Metal-Organic Frameworks for the Selective Adsorption of Noble Gases. In: Inorganic Chemistry. 2019.
@article{0549ef1c6f7942759314a0cad7e6be3a,
title = "Tuning the Channel Size and Structure Flexibility of Metal-Organic Frameworks for the Selective Adsorption of Noble Gases",
abstract = "Two ultramicroporous metal-organic frameworks, Zn(ox)0.5(trz) and Zn(ox)0.5(atrz) (ox = oxalate, trz = triazolate, and atrz = 3-aminotriazolate), have been synthesized and tested for the adsorptive separation of Xe and Kr. We demonstrate that the Xe/Kr adsorption selectivity relates to the pore size as well as the structure flexibility of the adsorbents.",
author = "Liang Yu and Shunshun Xiong and Yuhan Lin and Liangying Li and Junjie Peng and Wei Liu and Xiaoxi Huang and Hao Wang and Jing Li",
year = "2019",
month = "1",
day = "1",
doi = "10.1021/acs.inorgchem.9b02449",
language = "English",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",

}

TY - JOUR

T1 - Tuning the Channel Size and Structure Flexibility of Metal-Organic Frameworks for the Selective Adsorption of Noble Gases

AU - Yu, Liang

AU - Xiong, Shunshun

AU - Lin, Yuhan

AU - Li, Liangying

AU - Peng, Junjie

AU - Liu, Wei

AU - Huang, Xiaoxi

AU - Wang, Hao

AU - Li, Jing

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Two ultramicroporous metal-organic frameworks, Zn(ox)0.5(trz) and Zn(ox)0.5(atrz) (ox = oxalate, trz = triazolate, and atrz = 3-aminotriazolate), have been synthesized and tested for the adsorptive separation of Xe and Kr. We demonstrate that the Xe/Kr adsorption selectivity relates to the pore size as well as the structure flexibility of the adsorbents.

AB - Two ultramicroporous metal-organic frameworks, Zn(ox)0.5(trz) and Zn(ox)0.5(atrz) (ox = oxalate, trz = triazolate, and atrz = 3-aminotriazolate), have been synthesized and tested for the adsorptive separation of Xe and Kr. We demonstrate that the Xe/Kr adsorption selectivity relates to the pore size as well as the structure flexibility of the adsorbents.

UR - http://www.scopus.com/inward/record.url?scp=85073818849&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85073818849&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.9b02449

DO - 10.1021/acs.inorgchem.9b02449

M3 - Article

C2 - 31625727

AN - SCOPUS:85073818849

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -