Abstract
Separation of hydrocarbons is one of the most energy demanding processes. The need to develop materials for the selective adsorption of hydrocarbons, under reasonable conditions, is therefore of paramount importance. This work unveils unexpected hydrocarbon selectivity in a flexible Metal-Organic Framework (MOF), based on differences in their gate opening pressure. We show selectivity dependence on both chain length and specific framework-gas interaction. By combining Raman spectroscopy and theoretical van der Waals Density Functional (vdW-DF) calculations, the separation mechanisms governing this unexpected gate-opening behavior are revealed.
| Original language | English |
|---|---|
| Pages (from-to) | 15201-15204 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 134 |
| Issue number | 37 |
| DOIs | |
| Publication status | Published - Sep 19 2012 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Tuning the gate opening pressure of Metal-Organic Frameworks (MOFs) for the selective separation of hydrocarbons. / Nijem, Nour; Wu, Haohan; Canepa, Pieremanuele; Marti, Anne; Balkus, Kenneth J.; Thonhauser, Timo; Li, Jing; Chabal, Yves J.
In: Journal of the American Chemical Society, Vol. 134, No. 37, 19.09.2012, p. 15201-15204.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Tuning the gate opening pressure of Metal-Organic Frameworks (MOFs) for the selective separation of hydrocarbons
AU - Nijem, Nour
AU - Wu, Haohan
AU - Canepa, Pieremanuele
AU - Marti, Anne
AU - Balkus, Kenneth J.
AU - Thonhauser, Timo
AU - Li, Jing
AU - Chabal, Yves J.
PY - 2012/9/19
Y1 - 2012/9/19
N2 - Separation of hydrocarbons is one of the most energy demanding processes. The need to develop materials for the selective adsorption of hydrocarbons, under reasonable conditions, is therefore of paramount importance. This work unveils unexpected hydrocarbon selectivity in a flexible Metal-Organic Framework (MOF), based on differences in their gate opening pressure. We show selectivity dependence on both chain length and specific framework-gas interaction. By combining Raman spectroscopy and theoretical van der Waals Density Functional (vdW-DF) calculations, the separation mechanisms governing this unexpected gate-opening behavior are revealed.
AB - Separation of hydrocarbons is one of the most energy demanding processes. The need to develop materials for the selective adsorption of hydrocarbons, under reasonable conditions, is therefore of paramount importance. This work unveils unexpected hydrocarbon selectivity in a flexible Metal-Organic Framework (MOF), based on differences in their gate opening pressure. We show selectivity dependence on both chain length and specific framework-gas interaction. By combining Raman spectroscopy and theoretical van der Waals Density Functional (vdW-DF) calculations, the separation mechanisms governing this unexpected gate-opening behavior are revealed.
UR - http://www.scopus.com/inward/record.url?scp=84866516497&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84866516497&partnerID=8YFLogxK
U2 - 10.1021/ja305754f
DO - 10.1021/ja305754f
M3 - Article
C2 - 22946693
AN - SCOPUS:84866516497
VL - 134
SP - 15201
EP - 15204
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 37
ER -