Abstract
A series of isostructural noncatenated, water-stable zinc-based dipyridyl pillared-paddlewheel metal-organic frameworks (MOFs) was synthesized with tunable pore hydrophobicity. Pore hydrophobicity was engendered through dipyridyl ligands decorated with alkyl chains of varying length (methyl to hexyl). The most hydrophobic MOFs exhibited selective sorption of ethanol over water.
| Original language | English |
|---|---|
| Pages (from-to) | 2938-2942 |
| Number of pages | 5 |
| Journal | Crystal Growth and Design |
| Volume | 13 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Jul 3 2013 |
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ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Tuning the hydrophobicity of zinc dipyridyl paddlewheel metal-organic frameworks for selective sorption. / Weston, Mitchell H.; Delaquil, Amelia A.; Sarjeant, Amy A.; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.
In: Crystal Growth and Design, Vol. 13, No. 7, 03.07.2013, p. 2938-2942.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Tuning the hydrophobicity of zinc dipyridyl paddlewheel metal-organic frameworks for selective sorption
AU - Weston, Mitchell H.
AU - Delaquil, Amelia A.
AU - Sarjeant, Amy A.
AU - Farha, Omar K.
AU - Hupp, Joseph T
AU - Nguyen, Sonbinh T.
PY - 2013/7/3
Y1 - 2013/7/3
N2 - A series of isostructural noncatenated, water-stable zinc-based dipyridyl pillared-paddlewheel metal-organic frameworks (MOFs) was synthesized with tunable pore hydrophobicity. Pore hydrophobicity was engendered through dipyridyl ligands decorated with alkyl chains of varying length (methyl to hexyl). The most hydrophobic MOFs exhibited selective sorption of ethanol over water.
AB - A series of isostructural noncatenated, water-stable zinc-based dipyridyl pillared-paddlewheel metal-organic frameworks (MOFs) was synthesized with tunable pore hydrophobicity. Pore hydrophobicity was engendered through dipyridyl ligands decorated with alkyl chains of varying length (methyl to hexyl). The most hydrophobic MOFs exhibited selective sorption of ethanol over water.
UR - http://www.scopus.com/inward/record.url?scp=84879870473&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84879870473&partnerID=8YFLogxK
U2 - 10.1021/cg400342m
DO - 10.1021/cg400342m
M3 - Article
VL - 13
SP - 2938
EP - 2942
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 7
ER -