Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

Antigoni Douvali; Athanassios C. Tsipis; Svetlana V. Eliseeva; Stéphane Petoud; Giannis S. Papaefstathiou; Christos D. Malliakas; Ioannis Papadas; Gerasimos S. Armatas; Irene Margiolaki; Mercouri G. Kanatzidis; Theodore Lazarides; Manolis J. Manos

doi:10.1002/anie.201410612

Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

Antigoni Douvali, Athanassios C. Tsipis, Svetlana V. Eliseeva, Stéphane Petoud, Giannis S. Papaefstathiou, Christos D. Malliakas, Ioannis Papadas, Gerasimos S. Armatas, Irene Margiolaki, Mercouri G. Kanatzidis, Theodore Lazarides, Manolis J. Manos

Northwestern University

Research output: Contribution to journal › Article

148 Citations (Scopus)

Abstract

The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg²⁺ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

Original language	English
Pages (from-to)	1651-1656
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	5
DOIs	https://doi.org/10.1002/anie.201410612
Publication status	Published - Jan 26 2015

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Keywords

Crystal engineering
Luminescence
Metalorganic frameworks
Microporous materials
Sensors

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Douvali, A., Tsipis, A. C., Eliseeva, S. V., Petoud, S., Papaefstathiou, G. S., Malliakas, C. D., Papadas, I., Armatas, G. S., Margiolaki, I., Kanatzidis, M. G., Lazarides, T., & Manos, M. J. (2015). Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. Angewandte Chemie - International Edition, 54(5), 1651-1656. https://doi.org/10.1002/anie.201410612

Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. / Douvali, Antigoni; Tsipis, Athanassios C.; Eliseeva, Svetlana V.; Petoud, Stéphane; Papaefstathiou, Giannis S.; Malliakas, Christos D.; Papadas, Ioannis; Armatas, Gerasimos S.; Margiolaki, Irene; Kanatzidis, Mercouri G.; Lazarides, Theodore; Manos, Manolis J.

In: Angewandte Chemie - International Edition, Vol. 54, No. 5, 26.01.2015, p. 1651-1656.

Research output: Contribution to journal › Article

Douvali, A, Tsipis, AC, Eliseeva, SV, Petoud, S, Papaefstathiou, GS, Malliakas, CD, Papadas, I, Armatas, GS, Margiolaki, I, Kanatzidis, MG, Lazarides, T & Manos, MJ 2015, 'Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework', Angewandte Chemie - International Edition, vol. 54, no. 5, pp. 1651-1656. https://doi.org/10.1002/anie.201410612

Douvali, Antigoni ; Tsipis, Athanassios C. ; Eliseeva, Svetlana V. ; Petoud, Stéphane ; Papaefstathiou, Giannis S. ; Malliakas, Christos D. ; Papadas, Ioannis ; Armatas, Gerasimos S. ; Margiolaki, Irene ; Kanatzidis, Mercouri G. ; Lazarides, Theodore ; Manos, Manolis J. / Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. In: Angewandte Chemie - International Edition. 2015 ; Vol. 54, No. 5. pp. 1651-1656.

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Access to Document

10.1002/anie.201410612