Abstract
The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
| Original language | English |
|---|---|
| Pages (from-to) | 1651-1656 |
| Number of pages | 6 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 54 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Jan 26 2015 |
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Keywords
- Crystal engineering
- Luminescence
- Metalorganic frameworks
- Microporous materials
- Sensors
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. / Douvali, Antigoni; Tsipis, Athanassios C.; Eliseeva, Svetlana V.; Petoud, Stéphane; Papaefstathiou, Giannis S.; Malliakas, Christos D.; Papadas, Ioannis; Armatas, Gerasimos S.; Margiolaki, Irene; Kanatzidis, Mercouri G; Lazarides, Theodore; Manos, Manolis J.
In: Angewandte Chemie - International Edition, Vol. 54, No. 5, 26.01.2015, p. 1651-1656.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework
AU - Douvali, Antigoni
AU - Tsipis, Athanassios C.
AU - Eliseeva, Svetlana V.
AU - Petoud, Stéphane
AU - Papaefstathiou, Giannis S.
AU - Malliakas, Christos D.
AU - Papadas, Ioannis
AU - Armatas, Gerasimos S.
AU - Margiolaki, Irene
AU - Kanatzidis, Mercouri G
AU - Lazarides, Theodore
AU - Manos, Manolis J.
PY - 2015/1/26
Y1 - 2015/1/26
N2 - The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
AB - The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
KW - Crystal engineering
KW - Luminescence
KW - Metalorganic frameworks
KW - Microporous materials
KW - Sensors
UR - http://www.scopus.com/inward/record.url?scp=84921453296&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84921453296&partnerID=8YFLogxK
U2 - 10.1002/anie.201410612
DO - 10.1002/anie.201410612
M3 - Article
VL - 54
SP - 1651
EP - 1656
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 5
ER -