Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

Antigoni Douvali, Athanassios C. Tsipis, Svetlana V. Eliseeva, Stéphane Petoud, Giannis S. Papaefstathiou, Christos D. Malliakas, Ioannis Papadas, Gerasimos S. Armatas, Irene Margiolaki, Mercouri G Kanatzidis, Theodore Lazarides, Manolis J. Manos

Research output: Contribution to journalArticle

116 Citations (Scopus)

Abstract

The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

Original languageEnglish
Pages (from-to)1651-1656
Number of pages6
JournalAngewandte Chemie - International Edition
Volume54
Issue number5
DOIs
Publication statusPublished - Jan 26 2015

Fingerprint

Organic solvents
Luminescence
Metals
Water
Sensors
Reusability
Chemical industry
Water content

Keywords

  • Crystal engineering
  • Luminescence
  • Metalorganic frameworks
  • Microporous materials
  • Sensors

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Douvali, A., Tsipis, A. C., Eliseeva, S. V., Petoud, S., Papaefstathiou, G. S., Malliakas, C. D., ... Manos, M. J. (2015). Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. Angewandte Chemie - International Edition, 54(5), 1651-1656. https://doi.org/10.1002/anie.201410612

Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. / Douvali, Antigoni; Tsipis, Athanassios C.; Eliseeva, Svetlana V.; Petoud, Stéphane; Papaefstathiou, Giannis S.; Malliakas, Christos D.; Papadas, Ioannis; Armatas, Gerasimos S.; Margiolaki, Irene; Kanatzidis, Mercouri G; Lazarides, Theodore; Manos, Manolis J.

In: Angewandte Chemie - International Edition, Vol. 54, No. 5, 26.01.2015, p. 1651-1656.

Research output: Contribution to journalArticle

Douvali, A, Tsipis, AC, Eliseeva, SV, Petoud, S, Papaefstathiou, GS, Malliakas, CD, Papadas, I, Armatas, GS, Margiolaki, I, Kanatzidis, MG, Lazarides, T & Manos, MJ 2015, 'Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework', Angewandte Chemie - International Edition, vol. 54, no. 5, pp. 1651-1656. https://doi.org/10.1002/anie.201410612
Douvali, Antigoni ; Tsipis, Athanassios C. ; Eliseeva, Svetlana V. ; Petoud, Stéphane ; Papaefstathiou, Giannis S. ; Malliakas, Christos D. ; Papadas, Ioannis ; Armatas, Gerasimos S. ; Margiolaki, Irene ; Kanatzidis, Mercouri G ; Lazarides, Theodore ; Manos, Manolis J. / Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. In: Angewandte Chemie - International Edition. 2015 ; Vol. 54, No. 5. pp. 1651-1656.
@article{0a2b613d3b84400ab6b5e62bb76e6db8,
title = "Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework",
abstract = "The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5{\%} v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.",
keywords = "Crystal engineering, Luminescence, Metalorganic frameworks, Microporous materials, Sensors",
author = "Antigoni Douvali and Tsipis, {Athanassios C.} and Eliseeva, {Svetlana V.} and St{\'e}phane Petoud and Papaefstathiou, {Giannis S.} and Malliakas, {Christos D.} and Ioannis Papadas and Armatas, {Gerasimos S.} and Irene Margiolaki and Kanatzidis, {Mercouri G} and Theodore Lazarides and Manos, {Manolis J.}",
year = "2015",
month = "1",
day = "26",
doi = "10.1002/anie.201410612",
language = "English",
volume = "54",
pages = "1651--1656",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "5",

}

TY - JOUR

T1 - Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

AU - Douvali, Antigoni

AU - Tsipis, Athanassios C.

AU - Eliseeva, Svetlana V.

AU - Petoud, Stéphane

AU - Papaefstathiou, Giannis S.

AU - Malliakas, Christos D.

AU - Papadas, Ioannis

AU - Armatas, Gerasimos S.

AU - Margiolaki, Irene

AU - Kanatzidis, Mercouri G

AU - Lazarides, Theodore

AU - Manos, Manolis J.

PY - 2015/1/26

Y1 - 2015/1/26

N2 - The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

AB - The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

KW - Crystal engineering

KW - Luminescence

KW - Metalorganic frameworks

KW - Microporous materials

KW - Sensors

UR - http://www.scopus.com/inward/record.url?scp=84921453296&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84921453296&partnerID=8YFLogxK

U2 - 10.1002/anie.201410612

DO - 10.1002/anie.201410612

M3 - Article

C2 - 25487062

AN - SCOPUS:84921453296

VL - 54

SP - 1651

EP - 1656

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 5

ER -