Abstract
Four new azolium-containing metal - organic frameworks (MOFs) have been synthesized, where the azoliums are potential organocatalyst precursors. Modifying the number of azoliums on a standard biphenyl dicarboxylate strut affects the morphology or the degree of interpenetration in two representative types of MOFs: NbO-type Cu-paddlewheel 2D sheets and cubic IRMOFs.
| Original language | English |
|---|---|
| Pages (from-to) | 4747-4750 |
| Number of pages | 4 |
| Journal | Crystal Growth and Design |
| Volume | 11 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Nov 2 2011 |
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ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Two azolium rings are better than one : A strategy for controlling catenation and morphology in Zn and Cu metal - Organic frameworks. / Roberts, John M.; Farha, Omar K.; Sarjeant, Amy A.; Hupp, Joseph T; Scheidt, Karl A.
In: Crystal Growth and Design, Vol. 11, No. 11, 02.11.2011, p. 4747-4750.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Two azolium rings are better than one
T2 - A strategy for controlling catenation and morphology in Zn and Cu metal - Organic frameworks
AU - Roberts, John M.
AU - Farha, Omar K.
AU - Sarjeant, Amy A.
AU - Hupp, Joseph T
AU - Scheidt, Karl A.
PY - 2011/11/2
Y1 - 2011/11/2
N2 - Four new azolium-containing metal - organic frameworks (MOFs) have been synthesized, where the azoliums are potential organocatalyst precursors. Modifying the number of azoliums on a standard biphenyl dicarboxylate strut affects the morphology or the degree of interpenetration in two representative types of MOFs: NbO-type Cu-paddlewheel 2D sheets and cubic IRMOFs.
AB - Four new azolium-containing metal - organic frameworks (MOFs) have been synthesized, where the azoliums are potential organocatalyst precursors. Modifying the number of azoliums on a standard biphenyl dicarboxylate strut affects the morphology or the degree of interpenetration in two representative types of MOFs: NbO-type Cu-paddlewheel 2D sheets and cubic IRMOFs.
UR - http://www.scopus.com/inward/record.url?scp=82955245579&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=82955245579&partnerID=8YFLogxK
U2 - 10.1021/cg2011309
DO - 10.1021/cg2011309
M3 - Article
AN - SCOPUS:82955245579
VL - 11
SP - 4747
EP - 4750
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 11
ER -