Abstract
Two luminescent metal-organic-frameworks (LMOFs) constructed by a molecular chromophore [tri(4-pyridylphenyl)amine] (tppa) were synthesized by solvothermal reactions and characterized by single crystal and powder X-ray diffraction, thermogravimetric analysis, optical diffuse reflection, photoluminescence spectroscopy, and internal quantum yield measurements. Both compound 1 [Zn(tppa)(ndc)·(DMF)4] and compound 2 [Zn4(tppa)2(sdc)3(NO3)2·(DMF)4·(ACN)2] (ndc = 2,6-naphthalenedicarboxylic acid, sdc = (E)-4,4′-(ethene-1,2-diyl)dibenzoic acid, DMF = dimethylformamide, ACN = acetonitrile) exhibit intense yellow emission under blue light (455 nm) excitation. The Commission International de I'Eclairage (CIE) coordinates of 1 (0.42, 0.53) and 2 (0.42, 0.54) are close to that of YAG:Ce3+ (0.41, 0.55) (λex = 455 nm). The two phosphor materials show promise for use in phosphor-converted white LEDs (PC-WLEDs).
| Original language | English |
|---|---|
| Pages (from-to) | 956-961 |
| Number of pages | 6 |
| Journal | Dalton Transactions |
| Volume | 46 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Jan 1 2017 |
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ASJC Scopus subject areas
- Inorganic Chemistry
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Two blue-light excitable yellow-emitting LMOF phosphors constructed by triangular tri(4-pyridylphenyl)amine. / Wang, Fangming; Zhou, Zeyu; Liu, Wei; Zhou, Lei; Chen, Lizhuang; Li, Jing.
In: Dalton Transactions, Vol. 46, No. 3, 01.01.2017, p. 956-961.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Two blue-light excitable yellow-emitting LMOF phosphors constructed by triangular tri(4-pyridylphenyl)amine
AU - Wang, Fangming
AU - Zhou, Zeyu
AU - Liu, Wei
AU - Zhou, Lei
AU - Chen, Lizhuang
AU - Li, Jing
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Two luminescent metal-organic-frameworks (LMOFs) constructed by a molecular chromophore [tri(4-pyridylphenyl)amine] (tppa) were synthesized by solvothermal reactions and characterized by single crystal and powder X-ray diffraction, thermogravimetric analysis, optical diffuse reflection, photoluminescence spectroscopy, and internal quantum yield measurements. Both compound 1 [Zn(tppa)(ndc)·(DMF)4] and compound 2 [Zn4(tppa)2(sdc)3(NO3)2·(DMF)4·(ACN)2] (ndc = 2,6-naphthalenedicarboxylic acid, sdc = (E)-4,4′-(ethene-1,2-diyl)dibenzoic acid, DMF = dimethylformamide, ACN = acetonitrile) exhibit intense yellow emission under blue light (455 nm) excitation. The Commission International de I'Eclairage (CIE) coordinates of 1 (0.42, 0.53) and 2 (0.42, 0.54) are close to that of YAG:Ce3+ (0.41, 0.55) (λex = 455 nm). The two phosphor materials show promise for use in phosphor-converted white LEDs (PC-WLEDs).
AB - Two luminescent metal-organic-frameworks (LMOFs) constructed by a molecular chromophore [tri(4-pyridylphenyl)amine] (tppa) were synthesized by solvothermal reactions and characterized by single crystal and powder X-ray diffraction, thermogravimetric analysis, optical diffuse reflection, photoluminescence spectroscopy, and internal quantum yield measurements. Both compound 1 [Zn(tppa)(ndc)·(DMF)4] and compound 2 [Zn4(tppa)2(sdc)3(NO3)2·(DMF)4·(ACN)2] (ndc = 2,6-naphthalenedicarboxylic acid, sdc = (E)-4,4′-(ethene-1,2-diyl)dibenzoic acid, DMF = dimethylformamide, ACN = acetonitrile) exhibit intense yellow emission under blue light (455 nm) excitation. The Commission International de I'Eclairage (CIE) coordinates of 1 (0.42, 0.53) and 2 (0.42, 0.54) are close to that of YAG:Ce3+ (0.41, 0.55) (λex = 455 nm). The two phosphor materials show promise for use in phosphor-converted white LEDs (PC-WLEDs).
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U2 - 10.1039/c6dt03883b
DO - 10.1039/c6dt03883b
M3 - Article
VL - 46
SP - 956
EP - 961
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 3
ER -