Two large-pore metal-organic frameworks derived from a single polytopic strut

Ibrahim Eryazici; Omar K. Farha; Brad G. Hauser; A. Özgür Yazaydin; Amy A. Sarjeant; Sonbinh T. Nguyen; Joseph T. Hupp

doi:10.1021/cg201520z

Two large-pore metal-organic frameworks derived from a single polytopic strut

Ibrahim Eryazici, Omar K. Farha, Brad G. Hauser, A. Özgür Yazaydin, Amy A. Sarjeant, Sonbinh T. Nguyen, Joseph T. Hupp

Northwestern University

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn ₄O nodes in which all struts lie in a-b planes.

Original language	English
Pages (from-to)	1075-1080
Number of pages	6
Journal	Crystal Growth and Design
Volume	12
Issue number	3
DOIs	https://doi.org/10.1021/cg201520z
Publication status	Published - Mar 7 2012

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1021/cg201520z

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title = "Two large-pore metal-organic frameworks derived from a single polytopic strut",

abstract = "Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.",

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AU - Farha, Omar K.

AU - Hauser, Brad G.

AU - Yazaydin, A. Özgür

AU - Sarjeant, Amy A.

AU - Nguyen, Sonbinh T.

AU - Hupp, Joseph T.

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AB - Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.

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