Two large-pore metal-organic frameworks derived from a single polytopic strut

Ibrahim Eryazici, Omar K. Farha, Brad G. Hauser, A. Özgür Yazaydin, Amy A. Sarjeant, Sonbinh T. Nguyen, Joseph T Hupp

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.

Original languageEnglish
Pages (from-to)1075-1080
Number of pages6
JournalCrystal Growth and Design
Volume12
Issue number3
DOIs
Publication statusPublished - Mar 7 2012

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struts
Struts
Copper
Metals
Ions
porosity
copper
metals
spacers
Pore size
ions
topology
Ligands
Topology
ligands

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Eryazici, I., Farha, O. K., Hauser, B. G., Yazaydin, A. Ö., Sarjeant, A. A., Nguyen, S. T., & Hupp, J. T. (2012). Two large-pore metal-organic frameworks derived from a single polytopic strut. Crystal Growth and Design, 12(3), 1075-1080. https://doi.org/10.1021/cg201520z

Two large-pore metal-organic frameworks derived from a single polytopic strut. / Eryazici, Ibrahim; Farha, Omar K.; Hauser, Brad G.; Yazaydin, A. Özgür; Sarjeant, Amy A.; Nguyen, Sonbinh T.; Hupp, Joseph T.

In: Crystal Growth and Design, Vol. 12, No. 3, 07.03.2012, p. 1075-1080.

Research output: Contribution to journalArticle

Eryazici, I, Farha, OK, Hauser, BG, Yazaydin, AÖ, Sarjeant, AA, Nguyen, ST & Hupp, JT 2012, 'Two large-pore metal-organic frameworks derived from a single polytopic strut', Crystal Growth and Design, vol. 12, no. 3, pp. 1075-1080. https://doi.org/10.1021/cg201520z
Eryazici I, Farha OK, Hauser BG, Yazaydin AÖ, Sarjeant AA, Nguyen ST et al. Two large-pore metal-organic frameworks derived from a single polytopic strut. Crystal Growth and Design. 2012 Mar 7;12(3):1075-1080. https://doi.org/10.1021/cg201520z
Eryazici, Ibrahim ; Farha, Omar K. ; Hauser, Brad G. ; Yazaydin, A. Özgür ; Sarjeant, Amy A. ; Nguyen, Sonbinh T. ; Hupp, Joseph T. / Two large-pore metal-organic frameworks derived from a single polytopic strut. In: Crystal Growth and Design. 2012 ; Vol. 12, No. 3. pp. 1075-1080.
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