Abstract
Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.
| Original language | English |
|---|---|
| Pages (from-to) | 1075-1080 |
| Number of pages | 6 |
| Journal | Crystal Growth and Design |
| Volume | 12 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Mar 7 2012 |
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ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Two large-pore metal-organic frameworks derived from a single polytopic strut. / Eryazici, Ibrahim; Farha, Omar K.; Hauser, Brad G.; Yazaydin, A. Özgür; Sarjeant, Amy A.; Nguyen, Sonbinh T.; Hupp, Joseph T.
In: Crystal Growth and Design, Vol. 12, No. 3, 07.03.2012, p. 1075-1080.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Two large-pore metal-organic frameworks derived from a single polytopic strut
AU - Eryazici, Ibrahim
AU - Farha, Omar K.
AU - Hauser, Brad G.
AU - Yazaydin, A. Özgür
AU - Sarjeant, Amy A.
AU - Nguyen, Sonbinh T.
AU - Hupp, Joseph T
PY - 2012/3/7
Y1 - 2012/3/7
N2 - Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.
AB - Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.
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UR - http://www.scopus.com/inward/citedby.url?scp=84857982036&partnerID=8YFLogxK
U2 - 10.1021/cg201520z
DO - 10.1021/cg201520z
M3 - Article
VL - 12
SP - 1075
EP - 1080
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 3
ER -