Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands

Long Pan, Xiaoying Huang, Jing Li

Research output: Contribution to journalConference articlepeer-review

Abstract

The hydrothermal reactions of Cu(NO3)2·3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1̄, a = 5.358(1), b = 5.603(1), c = 13.515(3) Å, α = 81.78(3), β = 86.56(3), γ = 79.75(3)°, V = 394.91(13) Å3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) Å, β = 112.99(3)°, V = 2484.2(8) Å3, Z = 8.

Original languageEnglish
Pages (from-to)GG6171-GG6176
JournalMaterials Research Society Symposium - Proceedings
Volume658
Publication statusPublished - 2001
EventSolid - State Chemistry of Inorganic Materials III - Boston, MA, United States
Duration: Nov 27 2000Nov 30 2000

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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