Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands

Long Pan, Xiaoying Huang, Jing Li

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The hydrothermal reactions of Cu(NO3)2·3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1̄, a = 5.358(1), b = 5.603(1), c = 13.515(3) Å, α = 81.78(3), β = 86.56(3), γ = 79.75(3)°, V = 394.91(13) Å3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) Å, β = 112.99(3)°, V = 2484.2(8) Å3, Z = 8.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium - Proceedings
EditorsM Geselbracht, J Greedan, D Johnson, M A Subramanian
Volume658
Publication statusPublished - 2001
EventSolid - State Chemistry of Inorganic Materials III - Boston, MA, United States
Duration: Nov 27 2000Nov 30 2000

Other

OtherSolid - State Chemistry of Inorganic Materials III
CountryUnited States
CityBoston, MA
Period11/27/0011/30/00

Fingerprint

Ligands
Chromates
Anions
Cations
Copper
Ethylene
Negative ions
Positive ions
Crystals
4,4'-bipyridyl
ethylene

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Pan, L., Huang, X., & Li, J. (2001). Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands. In M. Geselbracht, J. Greedan, D. Johnson, & M. A. Subramanian (Eds.), Materials Research Society Symposium - Proceedings (Vol. 658)

Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands. / Pan, Long; Huang, Xiaoying; Li, Jing.

Materials Research Society Symposium - Proceedings. ed. / M Geselbracht; J Greedan; D Johnson; M A Subramanian. Vol. 658 2001.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Pan, L, Huang, X & Li, J 2001, Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands. in M Geselbracht, J Greedan, D Johnson & MA Subramanian (eds), Materials Research Society Symposium - Proceedings. vol. 658, Solid - State Chemistry of Inorganic Materials III, Boston, MA, United States, 11/27/00.
Pan L, Huang X, Li J. Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands. In Geselbracht M, Greedan J, Johnson D, Subramanian MA, editors, Materials Research Society Symposium - Proceedings. Vol. 658. 2001
Pan, Long ; Huang, Xiaoying ; Li, Jing. / Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands. Materials Research Society Symposium - Proceedings. editor / M Geselbracht ; J Greedan ; D Johnson ; M A Subramanian. Vol. 658 2001.
@inproceedings{144a403668d84e59b100ba34444b74cc,
title = "Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands",
abstract = "The hydrothermal reactions of Cu(NO3)2·3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1̄, a = 5.358(1), b = 5.603(1), c = 13.515(3) {\AA}, α = 81.78(3), β = 86.56(3), γ = 79.75(3)°, V = 394.91(13) {\AA}3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) {\AA}, β = 112.99(3)°, V = 2484.2(8) {\AA}3, Z = 8.",
author = "Long Pan and Xiaoying Huang and Jing Li",
year = "2001",
language = "English",
volume = "658",
editor = "M Geselbracht and J Greedan and D Johnson and Subramanian, {M A}",
booktitle = "Materials Research Society Symposium - Proceedings",

}

TY - GEN

T1 - Two pillared three-dimensional inorganic/organic hybrid structures composed of bimetallic layers bridged by exo-bidentate ligands

AU - Pan, Long

AU - Huang, Xiaoying

AU - Li, Jing

PY - 2001

Y1 - 2001

N2 - The hydrothermal reactions of Cu(NO3)2·3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1̄, a = 5.358(1), b = 5.603(1), c = 13.515(3) Å, α = 81.78(3), β = 86.56(3), γ = 79.75(3)°, V = 394.91(13) Å3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) Å, β = 112.99(3)°, V = 2484.2(8) Å3, Z = 8.

AB - The hydrothermal reactions of Cu(NO3)2·3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1̄, a = 5.358(1), b = 5.603(1), c = 13.515(3) Å, α = 81.78(3), β = 86.56(3), γ = 79.75(3)°, V = 394.91(13) Å3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) Å, β = 112.99(3)°, V = 2484.2(8) Å3, Z = 8.

UR - http://www.scopus.com/inward/record.url?scp=19244374595&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=19244374595&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:19244374595

VL - 658

BT - Materials Research Society Symposium - Proceedings

A2 - Geselbracht, M

A2 - Greedan, J

A2 - Johnson, D

A2 - Subramanian, M A

ER -