Two Regimes of Bandgap Red Shift and Partial Ambient Retention in Pressure-Treated Two-Dimensional Perovskites

Gang Liu, Lingping Kong, Peijun Guo, Constantinos C. Stoumpos, Qingyang Hu, Zhenxian Liu, Zhonghou Cai, David J. Gosztola, Ho Kwang Mao, Mercouri G Kanatzidis, Richard D Schaller

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

The discovery of elevated environmental stability in two-dimensional (2D) Ruddlesden-Popper hybrid perovskites represents a significant advance in low-cost, high-efficiency light absorbers. In comparison to 3D counterparts, 2D perovskites of organo-lead-halides exhibit wider, quantum-confined optical bandgaps that reduce the wavelength range of light absorption. Here, we characterize the structural and optical properties of 2D hybrid perovskites as a function of hydrostatic pressure. We observe bandgap narrowing with pressure of 633 meV that is partially retained following pressure release due to an atomic reconfiguration mechanism. We identify two distinct regimes of compression dominated by the softer organic and less compressible inorganic sublattices. Our findings, which also include PL enhancement, correlate well with density functional theory calculations and establish structure-property relationships at the atomic scale. These concepts can be expanded into other hybrid perovskites and suggest that pressure/strain processing could offer a new route to improved materials-by-design in applications.

Original languageEnglish
Pages (from-to)2518-2524
Number of pages7
JournalACS Energy Letters
Volume2
Issue number11
DOIs
Publication statusPublished - Nov 10 2017

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

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