Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Chandrani Ghosh; Thomas L. Groy; Amanda C. Bowman; Ryan Trovitch

doi:10.1039/c5cc09167e

Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Chandrani Ghosh, Thomas L. Groy, Amanda C. Bowman, Ryan Trovitch

Arizona State University

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

Reduction of 6-coordinate (^Ph2PPrDI)FeBr₂ under N₂ results in formation of the terminal dinitrogen complex, (^Ph2PPrDI)FeN₂. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ⁵-P,N,N,C_γ,P-^Ph2PPrDI^PrPPh)Fe]₂. Mechanistic possibilities for this transformation are discussed.

Original language	English
Pages (from-to)	4553-4556
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	24
DOIs	https://doi.org/10.1039/c5cc09167e
Publication status	Published - 2016

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ASJC Scopus subject areas

Chemistry(all)
Catalysis
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Surfaces, Coatings and Films
Materials Chemistry
Metals and Alloys

Cite this

Ghosh, C., Groy, T. L., Bowman, A. C., & Trovitch, R. (2016). Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex. Chemical Communications, 52(24), 4553-4556. https://doi.org/10.1039/c5cc09167e

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abstract = "Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.",

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AU - Trovitch, Ryan

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N2 - Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

AB - Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

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Access to Document

10.1039/c5cc09167e