Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Chandrani Ghosh, Thomas L. Groy, Amanda C. Bowman, Ryan Trovitch

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

Original languageEnglish
Pages (from-to)4553-4556
Number of pages4
JournalChemical Communications
Volume52
Issue number24
DOIs
Publication statusPublished - 2016

Fingerprint

Isomers
Iron
Chemical activation
Heating

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex. / Ghosh, Chandrani; Groy, Thomas L.; Bowman, Amanda C.; Trovitch, Ryan.

In: Chemical Communications, Vol. 52, No. 24, 2016, p. 4553-4556.

Research output: Contribution to journalArticle

Ghosh, Chandrani ; Groy, Thomas L. ; Bowman, Amanda C. ; Trovitch, Ryan. / Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex. In: Chemical Communications. 2016 ; Vol. 52, No. 24. pp. 4553-4556.
@article{89af487118774b298249aea2d76e715b,
title = "Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex",
abstract = "Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.",
author = "Chandrani Ghosh and Groy, {Thomas L.} and Bowman, {Amanda C.} and Ryan Trovitch",
year = "2016",
doi = "10.1039/c5cc09167e",
language = "English",
volume = "52",
pages = "4553--4556",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "24",

}

TY - JOUR

T1 - Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

AU - Ghosh, Chandrani

AU - Groy, Thomas L.

AU - Bowman, Amanda C.

AU - Trovitch, Ryan

PY - 2016

Y1 - 2016

N2 - Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

AB - Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

UR - http://www.scopus.com/inward/record.url?scp=84961285238&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84961285238&partnerID=8YFLogxK

U2 - 10.1039/c5cc09167e

DO - 10.1039/c5cc09167e

M3 - Article

VL - 52

SP - 4553

EP - 4556

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 24

ER -