Abstract
Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.
Original language | English |
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Pages (from-to) | 4553-4556 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 52 |
Issue number | 24 |
DOIs | |
Publication status | Published - Jan 1 2016 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry