Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Chandrani Ghosh, Thomas L. Groy, Amanda C. Bowman, Ryan Trovitch

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

Original languageEnglish
Pages (from-to)4553-4556
Number of pages4
JournalChemical Communications
Volume52
Issue number24
DOIs
Publication statusPublished - 2016

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Isomers
Iron
Chemical activation
Heating

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex. / Ghosh, Chandrani; Groy, Thomas L.; Bowman, Amanda C.; Trovitch, Ryan.

In: Chemical Communications, Vol. 52, No. 24, 2016, p. 4553-4556.

Research output: Contribution to journal › Article

Ghosh, C, Groy, TL, Bowman, AC & Trovitch, R 2016, 'Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex', Chemical Communications, vol. 52, no. 24, pp. 4553-4556. https://doi.org/10.1039/c5cc09167e
Ghosh C, Groy TL, Bowman AC, Trovitch R. Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex. Chemical Communications. 2016;52(24):4553-4556. https://doi.org/10.1039/c5cc09167e
Ghosh, Chandrani ; Groy, Thomas L. ; Bowman, Amanda C. ; Trovitch, Ryan. / Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex. In: Chemical Communications. 2016 ; Vol. 52, No. 24. pp. 4553-4556.
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