Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Chandrani Ghosh; Thomas L. Groy; Amanda C. Bowman; Ryan J. Trovitch

doi:10.1039/c5cc09167e

Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex

Chandrani Ghosh, Thomas L. Groy, Amanda C. Bowman, Ryan J. Trovitch

Arizona State University

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

Reduction of 6-coordinate (^Ph2PPrDI)FeBr₂ under N₂ results in formation of the terminal dinitrogen complex, (^Ph2PPrDI)FeN₂. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ⁵-P,N,N,C_γ,P-^Ph2PPrDI^PrPPh)Fe]₂. Mechanistic possibilities for this transformation are discussed.

Original language	English
Pages (from-to)	4553-4556
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	24
DOIs	https://doi.org/10.1039/c5cc09167e
Publication status	Published - Jan 1 2016

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Ghosh, C., Groy, T. L., Bowman, A. C., & Trovitch, R. J. (2016). Two-step C-H, C-P bond activation at an α-diimine iron dinitrogen complex. Chemical Communications, 52(24), 4553-4556. https://doi.org/10.1039/c5cc09167e

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abstract = "Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.",

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AU - Ghosh, Chandrani

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AU - Bowman, Amanda C.

AU - Trovitch, Ryan J.

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N2 - Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

AB - Reduction of 6-coordinate (Ph2PPrDI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, (Ph2PPrDI)FeN2. Heating this product to 75°C allows for C-H and C-P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ5-P,N,N,Cγ,P-Ph2PPrDIPrPPh)Fe]2. Mechanistic possibilities for this transformation are discussed.

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