Type-II quantum-dot-sensitized solar cell spanning the visible and near-infrared spectrum

Stella Itzhakov, Heping Shen, Sophia Buhbut, Hong Lin, Dan Oron

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

Type-II heterostructure CdTe/CdSe core/shell nanocrystals (quantum dots, QDs) are explored as sensitizers in a QD-sensitized photoelectrochemical solar cell. These QDs comprise a hole-localizing core and an electron-localizing shell. Among their advantages is the significant red shift of the absorption edge of the heterostructured QD relative to its two constituents due to spatially indirect absorption leading to improved absorption characteristics, intraparticle exciton dissociation upon photoexcitation, and a relatively small content of the less abundant tellurium element. Upon incorporation in a sensitized solar cell utilizing a porous TiO2 and a polysulfide electrolyte, these QDs exhibited efficient charge separation and high internal quantum efficiency despite hole localization in the CdTe core. Monochromatic incident photon-to-current conversion efficiency (IPCE) measurement shows a spectrally broad photoresponse spanning the whole visible spectrum and reaching up to ∼900 nm.

Original languageEnglish
Pages (from-to)22203-22210
Number of pages8
JournalJournal of Physical Chemistry C
Volume117
Issue number43
DOIs
Publication statusPublished - Oct 31 2013

Fingerprint

Semiconductor quantum dots
Solar cells
infrared spectra
solar cells
quantum dots
Infrared radiation
Tellurium
polysulfides
Polysulfides
Photoexcitation
tellurium
polarization (charge separation)
visible spectrum
Quantum efficiency
photoexcitation
Excitons
red shift
Nanocrystals
Electrolytes
Conversion efficiency

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Type-II quantum-dot-sensitized solar cell spanning the visible and near-infrared spectrum. / Itzhakov, Stella; Shen, Heping; Buhbut, Sophia; Lin, Hong; Oron, Dan.

In: Journal of Physical Chemistry C, Vol. 117, No. 43, 31.10.2013, p. 22203-22210.

Research output: Contribution to journalArticle

Itzhakov, Stella ; Shen, Heping ; Buhbut, Sophia ; Lin, Hong ; Oron, Dan. / Type-II quantum-dot-sensitized solar cell spanning the visible and near-infrared spectrum. In: Journal of Physical Chemistry C. 2013 ; Vol. 117, No. 43. pp. 22203-22210.
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