Ultra long-lived electron-hole separation within water-soluble colloidal ZnO nanocrystals: Prospective applications for solar energy production

Anna M. Cieślak; Mariia V. Pavliuk; Luca D'Amario; Mohamed Abdellah; Kamil Sokołowski; Urszula Rybinska; Daniel L.A. Fernandes; Michał K. Leszczyński; Fikret Mamedov; Ahmed M. El-Zhory; Jens Föhlinger; Alena Budinská; Małgorzata Wolska-Pietkiewicz; Leif Hammarström; Janusz Lewiński; Jacinto Sá

doi:10.1016/j.nanoen.2016.09.045

Ultra long-lived electron-hole separation within water-soluble colloidal ZnO nanocrystals: Prospective applications for solar energy production

Anna M. Cieślak, Mariia V. Pavliuk, Luca D'Amario, Mohamed Abdellah, Kamil Sokołowski, Urszula Rybinska, Daniel L.A. Fernandes, Michał K. Leszczyński, Fikret Mamedov, Ahmed M. El-Zhory, Jens Föhlinger, Alena Budinská, Małgorzata Wolska-Pietkiewicz, Leif Hammarström, Janusz Lewiński, Jacinto Sá

Uppsala University

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Zinc oxide was one of the first semiconductors used in dye-sensitized solar cells but its instability in aqueous media precludes its use for large-scale applications. Herein, we report on a novel ZnO nanocrystal material derived by an organometallic approach that is simultaneously stable and soluble in water due to its carboxylate oligoethylene glycol shell strongly anchored to the inorganic core by the head groups. The resulting unique inorganic core-organic shell interface also stabilizes the photo-generated hole, leading to a dramatic slowing down of charge recombination, which otherwise is a major hurdle in using nanostructured ZnO.

Original language	English
Pages (from-to)	187-192
Number of pages	6
Journal	Nano Energy
Volume	30
DOIs	https://doi.org/10.1016/j.nanoen.2016.09.045
Publication status	Published - Dec 1 2016

Keywords

Advanced laser based spectroscopy
Solar energy production prospectus
Ultra long-lived electron-hole separation
Water-soluble colloidal ZnO nanocrystals

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Materials Science(all)
Electrical and Electronic Engineering

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Cieślak, A. M., Pavliuk, M. V., D'Amario, L., Abdellah, M., Sokołowski, K., Rybinska, U., Fernandes, D. L. A., Leszczyński, M. K., Mamedov, F., El-Zhory, A. M., Föhlinger, J., Budinská, A., Wolska-Pietkiewicz, M., Hammarström, L., Lewiński, J., & Sá, J. (2016). Ultra long-lived electron-hole separation within water-soluble colloidal ZnO nanocrystals: Prospective applications for solar energy production. Nano Energy, 30, 187-192. https://doi.org/10.1016/j.nanoen.2016.09.045

Ultra long-lived electron-hole separation within water-soluble colloidal ZnO nanocrystals : Prospective applications for solar energy production. / Cieślak, Anna M.; Pavliuk, Mariia V.; D'Amario, Luca; Abdellah, Mohamed; Sokołowski, Kamil; Rybinska, Urszula; Fernandes, Daniel L.A.; Leszczyński, Michał K.; Mamedov, Fikret; El-Zhory, Ahmed M.; Föhlinger, Jens; Budinská, Alena; Wolska-Pietkiewicz, Małgorzata; Hammarström, Leif; Lewiński, Janusz; Sá, Jacinto.

In: Nano Energy, Vol. 30, 01.12.2016, p. 187-192.

Research output: Contribution to journal › Article › peer-review

Cieślak, AM, Pavliuk, MV, D'Amario, L, Abdellah, M, Sokołowski, K, Rybinska, U, Fernandes, DLA, Leszczyński, MK, Mamedov, F, El-Zhory, AM, Föhlinger, J, Budinská, A, Wolska-Pietkiewicz, M, Hammarström, L, Lewiński, J & Sá, J 2016, 'Ultra long-lived electron-hole separation within water-soluble colloidal ZnO nanocrystals: Prospective applications for solar energy production', Nano Energy, vol. 30, pp. 187-192. https://doi.org/10.1016/j.nanoen.2016.09.045

Cieślak, Anna M. ; Pavliuk, Mariia V. ; D'Amario, Luca ; Abdellah, Mohamed ; Sokołowski, Kamil ; Rybinska, Urszula ; Fernandes, Daniel L.A. ; Leszczyński, Michał K. ; Mamedov, Fikret ; El-Zhory, Ahmed M. ; Föhlinger, Jens ; Budinská, Alena ; Wolska-Pietkiewicz, Małgorzata ; Hammarström, Leif ; Lewiński, Janusz ; Sá, Jacinto. / Ultra long-lived electron-hole separation within water-soluble colloidal ZnO nanocrystals : Prospective applications for solar energy production. In: Nano Energy. 2016 ; Vol. 30. pp. 187-192.

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abstract = "Zinc oxide was one of the first semiconductors used in dye-sensitized solar cells but its instability in aqueous media precludes its use for large-scale applications. Herein, we report on a novel ZnO nanocrystal material derived by an organometallic approach that is simultaneously stable and soluble in water due to its carboxylate oligoethylene glycol shell strongly anchored to the inorganic core by the head groups. The resulting unique inorganic core-organic shell interface also stabilizes the photo-generated hole, leading to a dramatic slowing down of charge recombination, which otherwise is a major hurdle in using nanostructured ZnO.",

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