Understanding the role of AgNO 3 concentration and seed morphology in the achievement of tunable shape control in gold nanostars

Supriya Atta, Michael Beetz, Laura Fabris

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Gold nanostars are one of the most fascinating anisotropic nanoparticles. The morphology of a nanostar can be controlled by changing various synthetic parameters; however, the detailed growth mechanism is still not fully understood. Herein, we investigate this process in six-branched nanostars, focusing first on the properties of a single crystalline seed, which evolves to include penta-twinned defects as the gateway to anisotropic growth into the 6-branched morphology. In particular, we report on a high-yield seed-mediated protocol for the synthesis of these particles with high dimensional monodispersity in the presence of Triton-X, ascorbic acid, and AgNO 3 . Detailed spectroscopic and microscopic analyses have allowed the identification of several key intermediates in the growth process, revealing that it proceeds via penta-twinned intermediate seeds. Importantly, we report the first experimental evidence tracking the location of silver with sub-nanometer resolution and prove its role as a stabilizing agent in these highly branched nanostructures. Our results indicate that metallic silver on the spikes stabilizes the nanostar morphology and the remaining silver, present when AgNO 3 is added at a high concentration, deposits on the core and between the bases of neighboring spikes. Importantly, we also demonstrate the possibility of achieving dimensional monodispersity, reproducibility, and tunability in colloidal gold nanostars that are substantially higher than those previously reported, which could be leveraged to carry out holistic computational-experimental studies to understand, predict, and tailor their plasmonic response.

Original languageEnglish
Pages (from-to)2946-2958
Number of pages13
JournalNanoscale
Volume11
Issue number6
DOIs
Publication statusPublished - Feb 14 2019

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Silver
Gold
Seed
Gold Colloid
Excipients
Ascorbic acid
Ascorbic Acid
Nanostructures
Deposits
Nanoparticles
Crystalline materials
Defects

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Understanding the role of AgNO 3 concentration and seed morphology in the achievement of tunable shape control in gold nanostars . / Atta, Supriya; Beetz, Michael; Fabris, Laura.

In: Nanoscale, Vol. 11, No. 6, 14.02.2019, p. 2946-2958.

Research output: Contribution to journalArticle

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