Upcycling Single-Use Polyethylene into High-Quality Liquid Products

Gokhan Celik, Robert M. Kennedy, Ryan A. Hackler, Magali Ferrandon, Akalanka Tennakoon, Smita Patnaik, Anne M. Lapointe, Salai C. Ammal, Andreas Heyden, Frédéric A. Perras, Marek Pruski, Susannah L. Scott, Kenneth R. Poeppelmeier, Aaron D. Sadow, Massimiliano Delferro

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Our civilization relies on synthetic polymers for all aspects of modern life; yet, inefficient recycling and extremely slow environmental degradation of plastics are causing increasing concern about their widespread use. After a single use, many of these materials are currently treated as waste, underutilizing their inherent chemical and energy value. In this study, energy-rich polyethylene (PE) macromolecules are catalytically transformed into value-added products by hydrogenolysis using well-dispersed Pt nanoparticles (NPs) supported on SrTiO3 perovskite nanocuboids by atomic layer deposition. Pt/SrTiO3 completely converts PE (Mn = 8000-158,000 Da) or a single-use plastic bag (Mn = 31,000 Da) into high-quality liquid products, such as lubricants and waxes, characterized by a narrow distribution of oligomeric chains, at 170 psi H2 and 300 °C under solvent-free conditions for reaction durations up to 96 h. The binding of PE onto the catalyst surface contributes to the number averaged molecular weight (Mn) and the narrow polydispersity (D) of the final liquid product. Solid-state nuclear magnetic resonance of 13C-enriched PE adsorption studies and density functional theory computations suggest that PE adsorption is more favorable on Pt sites than that on the SrTiO3 support. Smaller Pt NPs with higher concentrations of undercoordinated Pt sites over-hydrogenolyzed PE to undesired light hydrocarbons.

Original languageEnglish
Pages (from-to)1795-1803
Number of pages9
JournalACS Central Science
Volume5
Issue number11
DOIs
Publication statusPublished - Nov 27 2019

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Polyethylene
Polyethylenes
Liquids
Plastics
Nanoparticles
Adsorption
Hydrogenolysis
Atomic layer deposition
Waxes
Polydispersity
Weathering
Hydrocarbons
Macromolecules
Perovskite
Density functional theory
Lubricants
Recycling
Polymers
Molecular weight
Nuclear magnetic resonance

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Celik, G., Kennedy, R. M., Hackler, R. A., Ferrandon, M., Tennakoon, A., Patnaik, S., ... Delferro, M. (2019). Upcycling Single-Use Polyethylene into High-Quality Liquid Products. ACS Central Science, 5(11), 1795-1803. https://doi.org/10.1021/acscentsci.9b00722

Upcycling Single-Use Polyethylene into High-Quality Liquid Products. / Celik, Gokhan; Kennedy, Robert M.; Hackler, Ryan A.; Ferrandon, Magali; Tennakoon, Akalanka; Patnaik, Smita; Lapointe, Anne M.; Ammal, Salai C.; Heyden, Andreas; Perras, Frédéric A.; Pruski, Marek; Scott, Susannah L.; Poeppelmeier, Kenneth R.; Sadow, Aaron D.; Delferro, Massimiliano.

In: ACS Central Science, Vol. 5, No. 11, 27.11.2019, p. 1795-1803.

Research output: Contribution to journalArticle

Celik, G, Kennedy, RM, Hackler, RA, Ferrandon, M, Tennakoon, A, Patnaik, S, Lapointe, AM, Ammal, SC, Heyden, A, Perras, FA, Pruski, M, Scott, SL, Poeppelmeier, KR, Sadow, AD & Delferro, M 2019, 'Upcycling Single-Use Polyethylene into High-Quality Liquid Products', ACS Central Science, vol. 5, no. 11, pp. 1795-1803. https://doi.org/10.1021/acscentsci.9b00722
Celik G, Kennedy RM, Hackler RA, Ferrandon M, Tennakoon A, Patnaik S et al. Upcycling Single-Use Polyethylene into High-Quality Liquid Products. ACS Central Science. 2019 Nov 27;5(11):1795-1803. https://doi.org/10.1021/acscentsci.9b00722
Celik, Gokhan ; Kennedy, Robert M. ; Hackler, Ryan A. ; Ferrandon, Magali ; Tennakoon, Akalanka ; Patnaik, Smita ; Lapointe, Anne M. ; Ammal, Salai C. ; Heyden, Andreas ; Perras, Frédéric A. ; Pruski, Marek ; Scott, Susannah L. ; Poeppelmeier, Kenneth R. ; Sadow, Aaron D. ; Delferro, Massimiliano. / Upcycling Single-Use Polyethylene into High-Quality Liquid Products. In: ACS Central Science. 2019 ; Vol. 5, No. 11. pp. 1795-1803.
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