Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices

Jingmei Shen; Kai Han; Elizabeth J. Martin; Yi Y. Wu; Mayfair C. Kung; Cary M. Hayner; Kenneth R. Shull; Harold H. Kung

doi:10.1039/c4ta04852k

Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices

Jingmei Shen, Kai Han, Elizabeth J. Martin, Yi Y. Wu, Mayfair C. Kung, Cary M. Hayner, Kenneth R. Shull, Harold H. Kung

Northwestern University

Research output: Contribution to journal › Article

20 Citations (Scopus)

Abstract

A thermally responsive membrane separator, suitable for use in non-aqueous electrolytes, was constructed by grafting a UCST polymer, poly(sulfobetaine), onto graphene oxide sheets. When heated from 20 to 80 °C, it decreased the specific storage capacity of the electrode for Li by >50% reversibly, compared to 30% increase without polymer modification.

Original language	English
Pages (from-to)	18204-18207
Number of pages	4
Journal	Journal of Materials Chemistry A
Volume	2
Issue number	43
DOIs	https://doi.org/10.1039/c4ta04852k
Publication status	Published - Nov 21 2014

ASJC Scopus subject areas

Chemistry(all)
Renewable Energy, Sustainability and the Environment
Materials Science(all)

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Shen, J., Han, K., Martin, E. J., Wu, Y. Y., Kung, M. C., Hayner, C. M., Shull, K. R., & Kung, H. H. (2014). Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices. Journal of Materials Chemistry A, 2(43), 18204-18207. https://doi.org/10.1039/c4ta04852k

Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices. / Shen, Jingmei; Han, Kai; Martin, Elizabeth J.; Wu, Yi Y.; Kung, Mayfair C.; Hayner, Cary M.; Shull, Kenneth R.; Kung, Harold H.

In: Journal of Materials Chemistry A, Vol. 2, No. 43, 21.11.2014, p. 18204-18207.

Research output: Contribution to journal › Article

Shen, Jingmei ; Han, Kai ; Martin, Elizabeth J. ; Wu, Yi Y. ; Kung, Mayfair C. ; Hayner, Cary M. ; Shull, Kenneth R. ; Kung, Harold H. / Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices. In: Journal of Materials Chemistry A. 2014 ; Vol. 2, No. 43. pp. 18204-18207.

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