Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices

Jingmei Shen, Kai Han, Elizabeth J. Martin, Yi Y. Wu, Mayfair C. Kung, Cary M. Hayner, Kenneth R. Shull, Harold H Kung

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A thermally responsive membrane separator, suitable for use in non-aqueous electrolytes, was constructed by grafting a UCST polymer, poly(sulfobetaine), onto graphene oxide sheets. When heated from 20 to 80 °C, it decreased the specific storage capacity of the electrode for Li by >50% reversibly, compared to 30% increase without polymer modification.

Original languageEnglish
Pages (from-to)18204-18207
Number of pages4
JournalJournal of Materials Chemistry A
Volume2
Issue number43
DOIs
Publication statusPublished - Nov 21 2014

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Energy storage
Oxides
Graphene
Polymers
Ions
Membranes
Separators
Electrolytes
Temperature
Electrodes
sulfobetaine

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices. / Shen, Jingmei; Han, Kai; Martin, Elizabeth J.; Wu, Yi Y.; Kung, Mayfair C.; Hayner, Cary M.; Shull, Kenneth R.; Kung, Harold H.

In: Journal of Materials Chemistry A, Vol. 2, No. 43, 21.11.2014, p. 18204-18207.

Research output: Contribution to journalArticle

Shen, Jingmei ; Han, Kai ; Martin, Elizabeth J. ; Wu, Yi Y. ; Kung, Mayfair C. ; Hayner, Cary M. ; Shull, Kenneth R. ; Kung, Harold H. / Upper-critical solution temperature (UCST) polymer functionalized graphene oxide as thermally responsive ion permeable membrane for energy storage devices. In: Journal of Materials Chemistry A. 2014 ; Vol. 2, No. 43. pp. 18204-18207.
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