Use of hydrazine in the hydrothermal synthesis of chalcogenides: The neutral framework material [M n2SnS 4H 4) 2]

Manolis J. Manos, Mercouri G. Kanatzidis

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Abstract

The reaction system MiVSn/S/hydrazine/water at ∼150°C afforded [Mn 2SnS 4(N 2H 4) 2] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL 6 (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn 2+ centers and ordering at ∼41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions.

Original languageEnglish
Pages (from-to)4658-4660
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number11
DOIs
Publication statusPublished - Jun 1 2009

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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