Abstract
Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast infrared detection, is a powerful technique for probing excited states and detecting reaction intermediates. In this Perspective we highlight the application of TRIR to excited states by probing the nature of the lowest excited states of fac-[Re(CO)3(dppz-Cl2)(R)]n+ (R = Cl- (n = 0), py (n = 1) and 4-Me2N-py (n = 1); dppz-Cl2 = 11,12-dichlorodipyrido-[3,2-a:2′,3′-c]phenazine) in CH3CN. The characterisation of [Cr(η6-C6H6)(CO)2Xe] and [Re(η5-C5H5)(CO)2(C2H 6)] in supercritical Xe and liquid ethane solution exemplifies how this technique can be applied to detect new organometallic species.
| Original language | English |
|---|---|
| Pages (from-to) | 3996-4006 |
| Number of pages | 11 |
| Journal | Journal of the Chemical Society, Dalton Transactions |
| Issue number | 21 |
| Publication status | Published - Nov 7 2003 |
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ASJC Scopus subject areas
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Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems. / Kuimova, Marina K.; Alsindi, Wassim Z.; Dyer, Joanne; Grills, David; Jina, Omar S.; Matousek, Pavel; Parker, Anthony W.; Portius, Peter; Sun, Xue Zhong; Towrie, Michael; Wilson, Claire; Yang, Jixin; George, Michael W.
In: Journal of the Chemical Society, Dalton Transactions, No. 21, 07.11.2003, p. 3996-4006.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems
AU - Kuimova, Marina K.
AU - Alsindi, Wassim Z.
AU - Dyer, Joanne
AU - Grills, David
AU - Jina, Omar S.
AU - Matousek, Pavel
AU - Parker, Anthony W.
AU - Portius, Peter
AU - Sun, Xue Zhong
AU - Towrie, Michael
AU - Wilson, Claire
AU - Yang, Jixin
AU - George, Michael W.
PY - 2003/11/7
Y1 - 2003/11/7
N2 - Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast infrared detection, is a powerful technique for probing excited states and detecting reaction intermediates. In this Perspective we highlight the application of TRIR to excited states by probing the nature of the lowest excited states of fac-[Re(CO)3(dppz-Cl2)(R)]n+ (R = Cl- (n = 0), py (n = 1) and 4-Me2N-py (n = 1); dppz-Cl2 = 11,12-dichlorodipyrido-[3,2-a:2′,3′-c]phenazine) in CH3CN. The characterisation of [Cr(η6-C6H6)(CO)2Xe] and [Re(η5-C5H5)(CO)2(C2H 6)] in supercritical Xe and liquid ethane solution exemplifies how this technique can be applied to detect new organometallic species.
AB - Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast infrared detection, is a powerful technique for probing excited states and detecting reaction intermediates. In this Perspective we highlight the application of TRIR to excited states by probing the nature of the lowest excited states of fac-[Re(CO)3(dppz-Cl2)(R)]n+ (R = Cl- (n = 0), py (n = 1) and 4-Me2N-py (n = 1); dppz-Cl2 = 11,12-dichlorodipyrido-[3,2-a:2′,3′-c]phenazine) in CH3CN. The characterisation of [Cr(η6-C6H6)(CO)2Xe] and [Re(η5-C5H5)(CO)2(C2H 6)] in supercritical Xe and liquid ethane solution exemplifies how this technique can be applied to detect new organometallic species.
UR - http://www.scopus.com/inward/record.url?scp=0242695595&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0242695595&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0242695595
SP - 3996
EP - 4006
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 21
ER -