Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems

Marina K. Kuimova, Wassim Z. Alsindi, Joanne Dyer, David Grills, Omar S. Jina, Pavel Matousek, Anthony W. Parker, Peter Portius, Xue Zhong Sun, Michael Towrie, Claire Wilson, Jixin Yang, Michael W. George

Research output: Contribution to journalArticle

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Abstract

Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast infrared detection, is a powerful technique for probing excited states and detecting reaction intermediates. In this Perspective we highlight the application of TRIR to excited states by probing the nature of the lowest excited states of fac-[Re(CO)3(dppz-Cl2)(R)]n+ (R = Cl- (n = 0), py (n = 1) and 4-Me2N-py (n = 1); dppz-Cl2 = 11,12-dichlorodipyrido-[3,2-a:2′,3′-c]phenazine) in CH3CN. The characterisation of [Cr(η6-C6H6)(CO)2Xe] and [Re(η5-C5H5)(CO)2(C2H 6)] in supercritical Xe and liquid ethane solution exemplifies how this technique can be applied to detect new organometallic species.

Original languageEnglish
Pages (from-to)3996-4006
Number of pages11
JournalJournal of the Chemical Society, Dalton Transactions
Issue number21
Publication statusPublished - Nov 7 2003

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Reaction intermediates
Carbon Monoxide
Excited states
Infrared spectroscopy
Infrared radiation
Ethane
Photolysis
Organometallics
Liquids

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems. / Kuimova, Marina K.; Alsindi, Wassim Z.; Dyer, Joanne; Grills, David; Jina, Omar S.; Matousek, Pavel; Parker, Anthony W.; Portius, Peter; Sun, Xue Zhong; Towrie, Michael; Wilson, Claire; Yang, Jixin; George, Michael W.

In: Journal of the Chemical Society, Dalton Transactions, No. 21, 07.11.2003, p. 3996-4006.

Research output: Contribution to journalArticle

Kuimova, MK, Alsindi, WZ, Dyer, J, Grills, D, Jina, OS, Matousek, P, Parker, AW, Portius, P, Sun, XZ, Towrie, M, Wilson, C, Yang, J & George, MW 2003, 'Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems', Journal of the Chemical Society, Dalton Transactions, no. 21, pp. 3996-4006.
Kuimova, Marina K. ; Alsindi, Wassim Z. ; Dyer, Joanne ; Grills, David ; Jina, Omar S. ; Matousek, Pavel ; Parker, Anthony W. ; Portius, Peter ; Sun, Xue Zhong ; Towrie, Michael ; Wilson, Claire ; Yang, Jixin ; George, Michael W. / Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems. In: Journal of the Chemical Society, Dalton Transactions. 2003 ; No. 21. pp. 3996-4006.
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AU - Jina, Omar S.

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AU - Parker, Anthony W.

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AU - Wilson, Claire

AU - Yang, Jixin

AU - George, Michael W.

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