Variable band filling and an insulator-to-metal transition in a structure-enforced molecular metal

Manuel Almeida, John Gaudiello, Tobin J Marks, John C. Butler, Henry O. Marcy, Carl R. Kannewurf

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Slurry electrochemical doping of the cofacially-joined phthalocyanine polymer [Si(Pc)O]n in Et4N+tosylate- /acetonitrile yields doped polymers of stoichiometry {[Si(Pc)O](tosylate)y}n, where y = 0.00 to 0.67. Charge transport data show a continous evolution of properties, from those of an insulator to those (at y {greater-than or approximate} 0.20) of a molecular metal.

Original languageEnglish
Pages (from-to)261-266
Number of pages6
JournalSynthetic Metals
Volume21
Issue number1-3
DOIs
Publication statusPublished - 1987

Fingerprint

Molecular structure
Transition metals
Polymers
molecular structure
Metals
transition metals
insulators
polymers
Acetonitrile
Stoichiometry
metals
acetonitrile
Charge transfer
stoichiometry
Doping (additives)
phthalocyanine

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Variable band filling and an insulator-to-metal transition in a structure-enforced molecular metal. / Almeida, Manuel; Gaudiello, John; Marks, Tobin J; Butler, John C.; Marcy, Henry O.; Kannewurf, Carl R.

In: Synthetic Metals, Vol. 21, No. 1-3, 1987, p. 261-266.

Research output: Contribution to journalArticle

Almeida, Manuel ; Gaudiello, John ; Marks, Tobin J ; Butler, John C. ; Marcy, Henry O. ; Kannewurf, Carl R. / Variable band filling and an insulator-to-metal transition in a structure-enforced molecular metal. In: Synthetic Metals. 1987 ; Vol. 21, No. 1-3. pp. 261-266.
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