Abstract
Vibrational energy relaxation of molecules adsorbed at single crystal metal surfaces is measured by populating excited vibrational levels with picosecond infrared pump pulses and probing the population by infrared-visible sum frequency generation. Energy relaxation of the v=1 levels of the C-O stretching mode in CO/Cu(100) and of the symmetric C-H stretching mode of CH3S/Ag(111) are discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 5-16 |
| Number of pages | 12 |
| Journal | Journal of Electron Spectroscopy and Related Phenomena |
| Volume | 54-55 |
| Issue number | C |
| DOIs | |
| Publication status | Published - 1990 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
- Surfaces and Interfaces
Cite this
Vibrational energy transfer to metal surfaces probed by sum generation : CO/Cu(100) and CH3S/Ag(111). / Harris, Alex; Levinos, N. J.; Rothberg, L.; Dubois, L. H.; Dhar, L.; Shane, S. F.; Morin, M.
In: Journal of Electron Spectroscopy and Related Phenomena, Vol. 54-55, No. C, 1990, p. 5-16.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Vibrational energy transfer to metal surfaces probed by sum generation
T2 - CO/Cu(100) and CH3S/Ag(111)
AU - Harris, Alex
AU - Levinos, N. J.
AU - Rothberg, L.
AU - Dubois, L. H.
AU - Dhar, L.
AU - Shane, S. F.
AU - Morin, M.
PY - 1990
Y1 - 1990
N2 - Vibrational energy relaxation of molecules adsorbed at single crystal metal surfaces is measured by populating excited vibrational levels with picosecond infrared pump pulses and probing the population by infrared-visible sum frequency generation. Energy relaxation of the v=1 levels of the C-O stretching mode in CO/Cu(100) and of the symmetric C-H stretching mode of CH3S/Ag(111) are discussed.
AB - Vibrational energy relaxation of molecules adsorbed at single crystal metal surfaces is measured by populating excited vibrational levels with picosecond infrared pump pulses and probing the population by infrared-visible sum frequency generation. Energy relaxation of the v=1 levels of the C-O stretching mode in CO/Cu(100) and of the symmetric C-H stretching mode of CH3S/Ag(111) are discussed.
UR - http://www.scopus.com/inward/record.url?scp=0011470485&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0011470485&partnerID=8YFLogxK
U2 - 10.1016/0368-2048(90)80196-H
DO - 10.1016/0368-2048(90)80196-H
M3 - Article
AN - SCOPUS:0011470485
VL - 54-55
SP - 5
EP - 16
JO - Journal of Electron Spectroscopy and Related Phenomena
JF - Journal of Electron Spectroscopy and Related Phenomena
SN - 0368-2048
IS - C
ER -