Abstract
Colloidal semiconductor nanocrystals, or "quantum dots" (QDs), have several optical and chemical properties that give them the potential to enable nonincremental increases in the efficiencies of many types of photocatalytic reactions relevant for energy conversion and organic synthesis. Colloidal photocatalysts have many desirable characteristics of both heterogeneous and homogeneous catalysts but come with their own particular set of challenges. This viewpoint outlines some of the obstacles one first encounters when driving reactions with these colloids and offers some strategies for overcoming these obstacles, including ways to extend their excited state lifetimes, prevent corrosion by photogenerated holes, and choose a surface chemistry and buffering system for maximum colloidal stability over a range of environmental conditions.
| Original language | English |
|---|---|
| Pages (from-to) | 3659-3670 |
| Number of pages | 12 |
| Journal | Inorganic Chemistry |
| Volume | 57 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Apr 2 2018 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
Cite this
Viewpoint : Challenges in Colloidal Photocatalysis and Some Strategies for Addressing Them. / Kodaimati, Mohamad S.; McClelland, Kevin P.; He, Chen; Lian, Shichen; Jiang, Yishu; Zhang, Zhengyi; Weiss, Emily A.
In: Inorganic Chemistry, Vol. 57, No. 7, 02.04.2018, p. 3659-3670.Research output: Contribution to journal › Review article
}
TY - JOUR
T1 - Viewpoint
T2 - Challenges in Colloidal Photocatalysis and Some Strategies for Addressing Them
AU - Kodaimati, Mohamad S.
AU - McClelland, Kevin P.
AU - He, Chen
AU - Lian, Shichen
AU - Jiang, Yishu
AU - Zhang, Zhengyi
AU - Weiss, Emily A
PY - 2018/4/2
Y1 - 2018/4/2
N2 - Colloidal semiconductor nanocrystals, or "quantum dots" (QDs), have several optical and chemical properties that give them the potential to enable nonincremental increases in the efficiencies of many types of photocatalytic reactions relevant for energy conversion and organic synthesis. Colloidal photocatalysts have many desirable characteristics of both heterogeneous and homogeneous catalysts but come with their own particular set of challenges. This viewpoint outlines some of the obstacles one first encounters when driving reactions with these colloids and offers some strategies for overcoming these obstacles, including ways to extend their excited state lifetimes, prevent corrosion by photogenerated holes, and choose a surface chemistry and buffering system for maximum colloidal stability over a range of environmental conditions.
AB - Colloidal semiconductor nanocrystals, or "quantum dots" (QDs), have several optical and chemical properties that give them the potential to enable nonincremental increases in the efficiencies of many types of photocatalytic reactions relevant for energy conversion and organic synthesis. Colloidal photocatalysts have many desirable characteristics of both heterogeneous and homogeneous catalysts but come with their own particular set of challenges. This viewpoint outlines some of the obstacles one first encounters when driving reactions with these colloids and offers some strategies for overcoming these obstacles, including ways to extend their excited state lifetimes, prevent corrosion by photogenerated holes, and choose a surface chemistry and buffering system for maximum colloidal stability over a range of environmental conditions.
UR - http://www.scopus.com/inward/record.url?scp=85044747424&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85044747424&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.7b03182
DO - 10.1021/acs.inorgchem.7b03182
M3 - Review article
AN - SCOPUS:85044747424
VL - 57
SP - 3659
EP - 3670
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 7
ER -