Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)-polypyridyl-catalyzed reduction of water

Wangkheimayum Marjit Singh, Mohammad Mirmohades, Reuben T. Jane, Travis A. White, Leif Hammarström, Anders Thapper, Reiner Lomoth, Sascha Ott

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Early intermediates of catalytic water reduction by a Co(ii)-polypyridyl species have been characterized. Electrochemical detection of the Co(iii)-hydride and time-resolved spectroscopic detection of the Co(i)-ligand intermediates provide an understanding of their reactivity in electrolytic or light-driven reduction of protons to hydrogen.

Original languageEnglish
Pages (from-to)8638-8640
Number of pages3
JournalChemical Communications
Volume49
Issue number77
DOIs
Publication statusPublished - Oct 7 2013

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Water
Hydrides
Protons
Hydrogen
Ligands

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)-polypyridyl-catalyzed reduction of water. / Singh, Wangkheimayum Marjit; Mirmohades, Mohammad; Jane, Reuben T.; White, Travis A.; Hammarström, Leif; Thapper, Anders; Lomoth, Reiner; Ott, Sascha.

In: Chemical Communications, Vol. 49, No. 77, 07.10.2013, p. 8638-8640.

Research output: Contribution to journalArticle

Singh, Wangkheimayum Marjit ; Mirmohades, Mohammad ; Jane, Reuben T. ; White, Travis A. ; Hammarström, Leif ; Thapper, Anders ; Lomoth, Reiner ; Ott, Sascha. / Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)-polypyridyl-catalyzed reduction of water. In: Chemical Communications. 2013 ; Vol. 49, No. 77. pp. 8638-8640.
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