Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation

Pravas Deria, Yongchul G. Chung, Randall Q. Snurr, Joseph T Hupp, Omar K. Farha

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

Original languageEnglish
Pages (from-to)5172-5176
Number of pages5
JournalChemical Science
Volume6
Issue number9
DOIs
Publication statusPublished - Jun 19 2015

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Stabilization
Metals
Ligands
Water
Hydrolysis
Chemical activation
Vapors

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation. / Deria, Pravas; Chung, Yongchul G.; Snurr, Randall Q.; Hupp, Joseph T; Farha, Omar K.

In: Chemical Science, Vol. 6, No. 9, 19.06.2015, p. 5172-5176.

Research output: Contribution to journalArticle

Deria, Pravas ; Chung, Yongchul G. ; Snurr, Randall Q. ; Hupp, Joseph T ; Farha, Omar K. / Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation. In: Chemical Science. 2015 ; Vol. 6, No. 9. pp. 5172-5176.
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