Water-stable zirconium-based metal-organic framework material with high-surface area and gas-storage capacities

Oleksii V. Gutov, Wojciech Bury, Diego A. Gomez-Gualdron, Vaiva Krungleviciute, David Fairen-Jimenez, Joseph E. Mondloch, Amy A. Sarjeant, Salih S. Al-Juaid, Randall Q. Snurr, Joseph T Hupp, Taner Yildirim, Omar K. Farha

Research output: Contribution to journalArticle

78 Citations (Scopus)

Abstract

We designed, synthesized, and characterized a new Zr-based metal-organic framework material, NU-1100, with a pore volume of 1.53ccg-1 and Brunauer-Emmett-Teller (BET) surface area of 4020m2g-1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2 adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65bar and 77K is 0.092gg-1, which corresponds to 43gL-1. The volumetric and gravimetric methane-storage capacities at 65bar and 298K are approximately 180vSTP/v and 0.27gg-1, respectively.

Original languageEnglish
JournalChemistry - A European Journal
DOIs
Publication statusAccepted/In press - 2014

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Methane
Adsorption isotherms
Zirconium
Hydrogen
Metals
Adsorption
Water
Temperature

Keywords

  • Gas storage
  • Hydrogen
  • Metal-organic frameworks
  • Methane
  • Zirconium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Gutov, O. V., Bury, W., Gomez-Gualdron, D. A., Krungleviciute, V., Fairen-Jimenez, D., Mondloch, J. E., ... Farha, O. K. (Accepted/In press). Water-stable zirconium-based metal-organic framework material with high-surface area and gas-storage capacities. Chemistry - A European Journal. https://doi.org/10.1002/chem.201402895

Water-stable zirconium-based metal-organic framework material with high-surface area and gas-storage capacities. / Gutov, Oleksii V.; Bury, Wojciech; Gomez-Gualdron, Diego A.; Krungleviciute, Vaiva; Fairen-Jimenez, David; Mondloch, Joseph E.; Sarjeant, Amy A.; Al-Juaid, Salih S.; Snurr, Randall Q.; Hupp, Joseph T; Yildirim, Taner; Farha, Omar K.

In: Chemistry - A European Journal, 2014.

Research output: Contribution to journalArticle

Gutov, OV, Bury, W, Gomez-Gualdron, DA, Krungleviciute, V, Fairen-Jimenez, D, Mondloch, JE, Sarjeant, AA, Al-Juaid, SS, Snurr, RQ, Hupp, JT, Yildirim, T & Farha, OK 2014, 'Water-stable zirconium-based metal-organic framework material with high-surface area and gas-storage capacities', Chemistry - A European Journal. https://doi.org/10.1002/chem.201402895
Gutov, Oleksii V. ; Bury, Wojciech ; Gomez-Gualdron, Diego A. ; Krungleviciute, Vaiva ; Fairen-Jimenez, David ; Mondloch, Joseph E. ; Sarjeant, Amy A. ; Al-Juaid, Salih S. ; Snurr, Randall Q. ; Hupp, Joseph T ; Yildirim, Taner ; Farha, Omar K. / Water-stable zirconium-based metal-organic framework material with high-surface area and gas-storage capacities. In: Chemistry - A European Journal. 2014.
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AU - Krungleviciute, Vaiva

AU - Fairen-Jimenez, David

AU - Mondloch, Joseph E.

AU - Sarjeant, Amy A.

AU - Al-Juaid, Salih S.

AU - Snurr, Randall Q.

AU - Hupp, Joseph T

AU - Yildirim, Taner

AU - Farha, Omar K.

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AB - We designed, synthesized, and characterized a new Zr-based metal-organic framework material, NU-1100, with a pore volume of 1.53ccg-1 and Brunauer-Emmett-Teller (BET) surface area of 4020m2g-1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2 adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65bar and 77K is 0.092gg-1, which corresponds to 43gL-1. The volumetric and gravimetric methane-storage capacities at 65bar and 298K are approximately 180vSTP/v and 0.27gg-1, respectively.

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KW - Methane

KW - Zirconium

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