Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities

Oleksii V. Gutov; Wojciech Bury; Diego A. Gomez-Gualdron; Vaiva Krungleviciute; David Fairen-Jimenez; Joseph E. Mondloch; Amy A. Sarjeant; Salih S. Al-Juaid; Randall Q. Snurr; Joseph T. Hupp; Taner Yildirim; Omar K. Farha

doi:10.1002/chem.201402895

Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities

Oleksii V. Gutov, Wojciech Bury, Diego A. Gomez-Gualdron, Vaiva Krungleviciute, David Fairen-Jimenez, Joseph E. Mondloch, Amy A. Sarjeant, Salih S. Al-Juaid, Randall Q. Snurr, Joseph T. Hupp, Taner Yildirim, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg⁻¹and Brunauer–Emmett–Teller (BET) surface area of 4020 m²g⁻¹; to our knowledge, currently the highest published for Zr-based MOFs. CH₄/CO₂/H₂adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g⁻¹, which corresponds to 43 g L⁻¹. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 v_STP/v and 0.27 g g⁻¹, respectively.

Original language	English
Pages (from-to)	12389-12393
Number of pages	5
Journal	Chemistry - A European Journal
Volume	20
Issue number	39
DOIs	https://doi.org/10.1002/chem.201402895
Publication status	Published - Sep 22 2014

Keywords

gas storage
hydrogen
metal–organic frameworks
methane
zirconium

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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Gutov, O. V., Bury, W., Gomez-Gualdron, D. A., Krungleviciute, V., Fairen-Jimenez, D., Mondloch, J. E., Sarjeant, A. A., Al-Juaid, S. S., Snurr, R. Q., Hupp, J. T., Yildirim, T., & Farha, O. K. (2014). Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities. Chemistry - A European Journal, 20(39), 12389-12393. https://doi.org/10.1002/chem.201402895

Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities. / Gutov, Oleksii V.; Bury, Wojciech; Gomez-Gualdron, Diego A.; Krungleviciute, Vaiva; Fairen-Jimenez, David; Mondloch, Joseph E.; Sarjeant, Amy A.; Al-Juaid, Salih S.; Snurr, Randall Q.; Hupp, Joseph T.; Yildirim, Taner; Farha, Omar K.

In: Chemistry - A European Journal, Vol. 20, No. 39, 22.09.2014, p. 12389-12393.

Research output: Contribution to journal › Article › peer-review

Gutov, OV, Bury, W, Gomez-Gualdron, DA, Krungleviciute, V, Fairen-Jimenez, D, Mondloch, JE, Sarjeant, AA, Al-Juaid, SS, Snurr, RQ, Hupp, JT, Yildirim, T & Farha, OK 2014, 'Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities', Chemistry - A European Journal, vol. 20, no. 39, pp. 12389-12393. https://doi.org/10.1002/chem.201402895

Gutov, Oleksii V. ; Bury, Wojciech ; Gomez-Gualdron, Diego A. ; Krungleviciute, Vaiva ; Fairen-Jimenez, David ; Mondloch, Joseph E. ; Sarjeant, Amy A. ; Al-Juaid, Salih S. ; Snurr, Randall Q. ; Hupp, Joseph T. ; Yildirim, Taner ; Farha, Omar K. / Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities. In: Chemistry - A European Journal. 2014 ; Vol. 20, No. 39. pp. 12389-12393.

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title = "Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities",

abstract = "We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg−1and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g−1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g−1, which corresponds to 43 g L−1. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g−1, respectively.",

keywords = "gas storage, hydrogen, metal–organic frameworks, methane, zirconium",

author = "Gutov, {Oleksii V.} and Wojciech Bury and Gomez-Gualdron, {Diego A.} and Vaiva Krungleviciute and David Fairen-Jimenez and Mondloch, {Joseph E.} and Sarjeant, {Amy A.} and Al-Juaid, {Salih S.} and Snurr, {Randall Q.} and Hupp, {Joseph T.} and Taner Yildirim and Farha, {Omar K.}",

note = "Funding Information: O.K.F., J.T.H., and R.Q.S. thank DOE ARPA-E and the Stanford Global Climate and Energy Project for support of work relevant to methane and CO2, respectively. T.Y. acknowledges support by the U.S. Department of Energy through BES Grant No. DE-FG02-08ER46522. W.B. acknowledges support from the Foundation for Polish Science through the “Kolumb” Program. D.F.J. acknowledges the Royal Society (UK) for a University Research Fellowship. This material is based on work supported by the National Science Foundation (grant CHE-1048773).",

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AU - Gutov, Oleksii V.

AU - Bury, Wojciech

AU - Gomez-Gualdron, Diego A.

AU - Krungleviciute, Vaiva

AU - Fairen-Jimenez, David

AU - Mondloch, Joseph E.

AU - Sarjeant, Amy A.

AU - Al-Juaid, Salih S.

AU - Snurr, Randall Q.

AU - Hupp, Joseph T.

AU - Yildirim, Taner

AU - Farha, Omar K.

N1 - Funding Information: O.K.F., J.T.H., and R.Q.S. thank DOE ARPA-E and the Stanford Global Climate and Energy Project for support of work relevant to methane and CO2, respectively. T.Y. acknowledges support by the U.S. Department of Energy through BES Grant No. DE-FG02-08ER46522. W.B. acknowledges support from the Foundation for Polish Science through the “Kolumb” Program. D.F.J. acknowledges the Royal Society (UK) for a University Research Fellowship. This material is based on work supported by the National Science Foundation (grant CHE-1048773).

PY - 2014/9/22

Y1 - 2014/9/22

N2 - We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg−1and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g−1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g−1, which corresponds to 43 g L−1. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g−1, respectively.

AB - We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg−1and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g−1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g−1, which corresponds to 43 g L−1. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g−1, respectively.

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KW - hydrogen

KW - metal–organic frameworks

KW - methane

KW - zirconium

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