Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities

Oleksii V. Gutov; Wojciech Bury; Diego A. Gomez-Gualdron; Vaiva Krungleviciute; David Fairen-Jimenez; Joseph E. Mondloch; Amy A. Sarjeant; Salih S. Al-Juaid; Randall Q. Snurr; Joseph T. Hupp; Taner Yildirim; Omar K. Farha

doi:10.1002/chem.201402895

Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities

Oleksii V. Gutov, Wojciech Bury, Diego A. Gomez-Gualdron, Vaiva Krungleviciute, David Fairen-Jimenez, Joseph E. Mondloch, Amy A. Sarjeant, Salih S. Al-Juaid, Randall Q. Snurr, Joseph T. Hupp, Taner Yildirim, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article

96 Citations (Scopus)

Abstract

We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg⁻¹and Brunauer–Emmett–Teller (BET) surface area of 4020 m²g⁻¹; to our knowledge, currently the highest published for Zr-based MOFs. CH₄/CO₂/H₂adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g⁻¹, which corresponds to 43 g L⁻¹. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 v_STP/v and 0.27 g g⁻¹, respectively.

Original language	English
Pages (from-to)	12389-12393
Number of pages	5
Journal	Chemistry - A European Journal
Volume	20
Issue number	39
DOIs	https://doi.org/10.1002/chem.201402895
Publication status	Published - Jan 1 2014

Keywords

gas storage
hydrogen
metal–organic frameworks
methane
zirconium

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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Gutov, O. V., Bury, W., Gomez-Gualdron, D. A., Krungleviciute, V., Fairen-Jimenez, D., Mondloch, J. E., Sarjeant, A. A., Al-Juaid, S. S., Snurr, R. Q., Hupp, J. T., Yildirim, T., & Farha, O. K. (2014). Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities. Chemistry - A European Journal, 20(39), 12389-12393. https://doi.org/10.1002/chem.201402895

Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities. / Gutov, Oleksii V.; Bury, Wojciech; Gomez-Gualdron, Diego A.; Krungleviciute, Vaiva; Fairen-Jimenez, David; Mondloch, Joseph E.; Sarjeant, Amy A.; Al-Juaid, Salih S.; Snurr, Randall Q.; Hupp, Joseph T.; Yildirim, Taner; Farha, Omar K.

In: Chemistry - A European Journal, Vol. 20, No. 39, 01.01.2014, p. 12389-12393.

Research output: Contribution to journal › Article

Gutov, OV, Bury, W, Gomez-Gualdron, DA, Krungleviciute, V, Fairen-Jimenez, D, Mondloch, JE, Sarjeant, AA, Al-Juaid, SS, Snurr, RQ, Hupp, JT, Yildirim, T & Farha, OK 2014, 'Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities', Chemistry - A European Journal, vol. 20, no. 39, pp. 12389-12393. https://doi.org/10.1002/chem.201402895

Gutov, Oleksii V. ; Bury, Wojciech ; Gomez-Gualdron, Diego A. ; Krungleviciute, Vaiva ; Fairen-Jimenez, David ; Mondloch, Joseph E. ; Sarjeant, Amy A. ; Al-Juaid, Salih S. ; Snurr, Randall Q. ; Hupp, Joseph T. ; Yildirim, Taner ; Farha, Omar K. / Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities. In: Chemistry - A European Journal. 2014 ; Vol. 20, No. 39. pp. 12389-12393.

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abstract = "We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg−1and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g−1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g−1, which corresponds to 43 g L−1. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g−1, respectively.",

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AU - Krungleviciute, Vaiva

AU - Fairen-Jimenez, David

AU - Mondloch, Joseph E.

AU - Sarjeant, Amy A.

AU - Al-Juaid, Salih S.

AU - Snurr, Randall Q.

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AB - We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg−1and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g−1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g−1, which corresponds to 43 g L−1. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g−1, respectively.

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KW - zirconium

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