TY - JOUR
T1 - Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities
AU - Gutov, Oleksii V.
AU - Bury, Wojciech
AU - Gomez-Gualdron, Diego A.
AU - Krungleviciute, Vaiva
AU - Fairen-Jimenez, David
AU - Mondloch, Joseph E.
AU - Sarjeant, Amy A.
AU - Al-Juaid, Salih S.
AU - Snurr, Randall Q.
AU - Hupp, Joseph T.
AU - Yildirim, Taner
AU - Farha, Omar K.
N1 - Funding Information:
O.K.F., J.T.H., and R.Q.S. thank DOE ARPA-E and the Stanford Global Climate and Energy Project for support of work relevant to methane and CO2, respectively. T.Y. acknowledges support by the U.S. Department of Energy through BES Grant No. DE-FG02-08ER46522. W.B. acknowledges support from the Foundation for Polish Science through the “Kolumb” Program. D.F.J. acknowledges the Royal Society (UK) for a University Research Fellowship. This material is based on work supported by the National Science Foundation (grant CHE-1048773).
Publisher Copyright:
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2014/9/22
Y1 - 2014/9/22
N2 - We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg−1and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g−1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g−1, which corresponds to 43 g L−1. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g−1, respectively.
AB - We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg−1and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g−1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g−1, which corresponds to 43 g L−1. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g−1, respectively.
KW - gas storage
KW - hydrogen
KW - metal–organic frameworks
KW - methane
KW - zirconium
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U2 - 10.1002/chem.201402895
DO - 10.1002/chem.201402895
M3 - Article
AN - SCOPUS:84905758864
VL - 20
SP - 12389
EP - 12393
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 39
ER -