What can metal-ligand bonding energetics teach us about stoichiometric and catalytic organometallic chemistry?

Tobin J Marks, Michel Gagne, Steven Nolan, Schock Laurel, Afif Seyam, David Stern

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

This contribution surveys recent progress in the thermochemistry of lanthanide, actinide, and early transition element organometallic compounds. General trends in metal-ligand bond enthalpy patterns across the transition series can be understood largely on the basis of straightforward electronegativity concepts. Metal-ligand bonding energetics in such unusual species as metallacycles, early transition element carbonyls and benzynes, as well as in actinide carbonyls are also quantified. Such data furthermore provide a deeper insight into d0, f0- centered β-hydride/β-alkyl elimination, cyclometalation, and hydrocarbon functionalization processes, as well as into U(IV)-centered elimination reactions. New reactions which are examined in the light of metal-ligand bond enthalpy data include binuclear organolanthanide-centered hydrocarbon activation and organo- lanthanide-catalyzed hydroamination of olefins.

Original languageEnglish
Pages (from-to)1665-1672
Number of pages8
JournalPure and Applied Chemistry
Volume61
Issue number10
DOIs
Publication statusPublished - Jan 1 1989

Fingerprint

Transition Elements
Organometallics
Actinoid Series Elements
Lanthanoid Series Elements
Actinides
Metals
Ligands
Hydrocarbons
Rare earth elements
Chemical elements
Enthalpy
Light Metals
Organometallic Compounds
Thermochemistry
Electronegativity
Alkenes
Hydrides
Olefins
Chemical activation

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

What can metal-ligand bonding energetics teach us about stoichiometric and catalytic organometallic chemistry? / Marks, Tobin J; Gagne, Michel; Nolan, Steven; Laurel, Schock; Seyam, Afif; Stern, David.

In: Pure and Applied Chemistry, Vol. 61, No. 10, 01.01.1989, p. 1665-1672.

Research output: Contribution to journalArticle

Marks, Tobin J ; Gagne, Michel ; Nolan, Steven ; Laurel, Schock ; Seyam, Afif ; Stern, David. / What can metal-ligand bonding energetics teach us about stoichiometric and catalytic organometallic chemistry?. In: Pure and Applied Chemistry. 1989 ; Vol. 61, No. 10. pp. 1665-1672.
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