What can metal-ligand bonding energetics teach us about stoichiometric and catalytic organometallic chemistry?

Tobin J Marks, Michel Gagne, Steven Nolan, Schock Laurel, Afif Seyam, David Stern

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Abstract

This contribution surveys recent progress in the thermochemistry of lanthanide, actinide, and early transition element organometallic compounds. General trends in metal-ligand bond enthalpy patterns across the transition series can be understood largely on the basis of straightforward electronegativity concepts. Metal-ligand bonding energetics in such unusual species as metallacycles, early transition element carbonyls and benzynes, as well as in actinide carbonyls are also quantified. Such data furthermore provide a deeper insight into d0, f0- centered β-hydride/β-alkyl elimination, cyclometalation, and hydrocarbon functionalization processes, as well as into U(IV)-centered elimination reactions. New reactions which are examined in the light of metal-ligand bond enthalpy data include binuclear organolanthanide-centered hydrocarbon activation and organo- lanthanide-catalyzed hydroamination of olefins.

Original languageEnglish
Pages (from-to)1665-1672
Number of pages8
JournalPure and Applied Chemistry
Volume61
Issue number10
DOIs
Publication statusPublished - Jan 1 1989

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ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

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