Abstract
The cofacially joined metallomacrocyclic polymer [Si(Pc)O]n (Pc = phthalocyaninato) can be reversibly oxidized electrochemically as a slurry to yield a "molecular metal". As monitored by controlled potential coulometry, X-ray powder diffraction, infrared spectroscopy, specular reflectance spectroscopy, and thermoelectric power, the stoichiometry of the resulting {[Si(Pc)O](BF4)y}n polymers can be continuously varied from y = 0.00 to 0.50. This broad, incremental tuning of the band filling (the first time for a molecular metal) is accompanied by a continuous evolution of the optical and charge transport properties from those of a semiconductor to those of a low-dimensional metal-like material.
| Original language | English |
|---|---|
| Pages (from-to) | 4917-4920 |
| Number of pages | 4 |
| Journal | Journal of Physical Chemistry |
| Volume | 90 |
| Issue number | 21 |
| Publication status | Published - 1986 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
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Gaudiello, J. G., Almeida, M., Marks, T. J., McCarthy, W. J., Butler, J. C., & Kannewurf, C. R. (1986). Widely tunable band filling in a molecular metal. Chemical and physical consequences of electrochemically doping a cofacially joined metallomacrocyclic assembly. Journal of Physical Chemistry, 90(21), 4917-4920.