Yb8Ge3Sb5, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric 1[Ge 34-] Anions

James R. Salvador, Daniel Bilc, S. D. Mahanti, Tim Hogan, Fu Guo, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Yb8Ge3Sb5 is a nonclassical Zintl phase with metallic properties arising from the electropositive "spectator" cations of Yb. This compound contains the new Zintl anion 1α(Ge3)4- and is stabilized via a combination of Yb2+ and Yb3+ ions.

Original languageEnglish
Pages (from-to)4474-4475
Number of pages2
JournalJournal of the American Chemical Society
Volume126
Issue number14
DOIs
Publication statusPublished - Apr 14 2004

Fingerprint

Anions
Cations
Negative ions
Positive ions
Ions

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Yb8Ge3Sb5, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric 1[Ge 34-] Anions. / Salvador, James R.; Bilc, Daniel; Mahanti, S. D.; Hogan, Tim; Guo, Fu; Kanatzidis, Mercouri G.

In: Journal of the American Chemical Society, Vol. 126, No. 14, 14.04.2004, p. 4474-4475.

Research output: Contribution to journalArticle

Salvador, James R. ; Bilc, Daniel ; Mahanti, S. D. ; Hogan, Tim ; Guo, Fu ; Kanatzidis, Mercouri G. / Yb8Ge3Sb5, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric 1[Ge 34-] Anions. In: Journal of the American Chemical Society. 2004 ; Vol. 126, No. 14. pp. 4474-4475.
@article{34c31b2a4fe14f9f833a12a828ef993e,
title = "Yb8Ge3Sb5, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric 1∞[Ge 34-] Anions",
abstract = "Yb8Ge3Sb5 is a nonclassical Zintl phase with metallic properties arising from the electropositive {"}spectator{"} cations of Yb. This compound contains the new Zintl anion 1α(Ge3)4- and is stabilized via a combination of Yb2+ and Yb3+ ions.",
author = "Salvador, {James R.} and Daniel Bilc and Mahanti, {S. D.} and Tim Hogan and Fu Guo and Kanatzidis, {Mercouri G}",
year = "2004",
month = "4",
day = "14",
doi = "10.1021/ja0395487",
language = "English",
volume = "126",
pages = "4474--4475",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "14",

}

TY - JOUR

T1 - Yb8Ge3Sb5, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric 1∞[Ge 34-] Anions

AU - Salvador, James R.

AU - Bilc, Daniel

AU - Mahanti, S. D.

AU - Hogan, Tim

AU - Guo, Fu

AU - Kanatzidis, Mercouri G

PY - 2004/4/14

Y1 - 2004/4/14

N2 - Yb8Ge3Sb5 is a nonclassical Zintl phase with metallic properties arising from the electropositive "spectator" cations of Yb. This compound contains the new Zintl anion 1α(Ge3)4- and is stabilized via a combination of Yb2+ and Yb3+ ions.

AB - Yb8Ge3Sb5 is a nonclassical Zintl phase with metallic properties arising from the electropositive "spectator" cations of Yb. This compound contains the new Zintl anion 1α(Ge3)4- and is stabilized via a combination of Yb2+ and Yb3+ ions.

UR - http://www.scopus.com/inward/record.url?scp=1842688364&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1842688364&partnerID=8YFLogxK

U2 - 10.1021/ja0395487

DO - 10.1021/ja0395487

M3 - Article

C2 - 15070338

AN - SCOPUS:1842688364

VL - 126

SP - 4474

EP - 4475

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 14

ER -