Abstract
Gerss and Jeitschko recently synthesized YCoC, which contains well-isolated infinite linear CoC3- chains, marked by a short Co-C distance. We have examined the bonding in this polymer. It has substantial π character, and that bonding could be strengthened by decreasing the electron count or oxidation. We think the chains should be magnetic.
| Original language | English |
|---|---|
| Pages (from-to) | 6600-6602 |
| Number of pages | 3 |
| Journal | Journal of the American Chemical Society |
| Volume | 109 |
| Issue number | 22 |
| Publication status | Published - 1987 |
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ASJC Scopus subject areas
- Chemistry(all)
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YCoC : A simple organometallic polymer in the solid state with strong Co-C π bonding. / Hoffmann, Roald; Li, Jing; Wheeler, Ralph A.
In: Journal of the American Chemical Society, Vol. 109, No. 22, 1987, p. 6600-6602.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - YCoC
T2 - A simple organometallic polymer in the solid state with strong Co-C π bonding
AU - Hoffmann, Roald
AU - Li, Jing
AU - Wheeler, Ralph A.
PY - 1987
Y1 - 1987
N2 - Gerss and Jeitschko recently synthesized YCoC, which contains well-isolated infinite linear CoC3- chains, marked by a short Co-C distance. We have examined the bonding in this polymer. It has substantial π character, and that bonding could be strengthened by decreasing the electron count or oxidation. We think the chains should be magnetic.
AB - Gerss and Jeitschko recently synthesized YCoC, which contains well-isolated infinite linear CoC3- chains, marked by a short Co-C distance. We have examined the bonding in this polymer. It has substantial π character, and that bonding could be strengthened by decreasing the electron count or oxidation. We think the chains should be magnetic.
UR - http://www.scopus.com/inward/record.url?scp=0000306718&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000306718&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0000306718
VL - 109
SP - 6600
EP - 6602
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 22
ER -