Abstract
We present the synthesis, crystal structure, spectroscopic properties, and electronic structure of a new member of the Zintl family, Yb5Al 2Sb6. The compound crystallizes in the Ba 5Al2Bi6 structure type. A preliminary assessment of its thermoelectric properties including electrical conductivity, thermopower, and thermal conductivity are reported. Moreover, investigations of solid solutions of this phase, doping effects and chemical modifications will be presented. The room temperature conductivity, thermopower and thermal conductivity of Yb5Al2Sb6/0.5Ge were 1100 S/cm, 20μ V/K, and 3.8 W/m K, respectively.
| Original language | English |
|---|---|
| Title of host publication | Materials Research Society Symposium Proceedings |
| Pages | 199-204 |
| Number of pages | 6 |
| Volume | 1044 |
| Publication status | Published - 2008 |
| Event | Thermoelectric Power Generation - Boston, MA, United States Duration: Nov 26 2007 → Nov 29 2007 |
Other
| Other | Thermoelectric Power Generation |
|---|---|
| Country | United States |
| City | Boston, MA |
| Period | 11/26/07 → 11/29/07 |
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ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
- Mechanical Engineering
- Mechanics of Materials
Cite this
Zintl phase as thermoelectric materials : Synthesis, structure and properties of Yb5Al2Sb6. / Todorov, Iliya; Chung, Duck Young; Kanatzidis, Mercouri G.
Materials Research Society Symposium Proceedings. Vol. 1044 2008. p. 199-204.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Zintl phase as thermoelectric materials
T2 - Synthesis, structure and properties of Yb5Al2Sb6
AU - Todorov, Iliya
AU - Chung, Duck Young
AU - Kanatzidis, Mercouri G
PY - 2008
Y1 - 2008
N2 - We present the synthesis, crystal structure, spectroscopic properties, and electronic structure of a new member of the Zintl family, Yb5Al 2Sb6. The compound crystallizes in the Ba 5Al2Bi6 structure type. A preliminary assessment of its thermoelectric properties including electrical conductivity, thermopower, and thermal conductivity are reported. Moreover, investigations of solid solutions of this phase, doping effects and chemical modifications will be presented. The room temperature conductivity, thermopower and thermal conductivity of Yb5Al2Sb6/0.5Ge were 1100 S/cm, 20μ V/K, and 3.8 W/m K, respectively.
AB - We present the synthesis, crystal structure, spectroscopic properties, and electronic structure of a new member of the Zintl family, Yb5Al 2Sb6. The compound crystallizes in the Ba 5Al2Bi6 structure type. A preliminary assessment of its thermoelectric properties including electrical conductivity, thermopower, and thermal conductivity are reported. Moreover, investigations of solid solutions of this phase, doping effects and chemical modifications will be presented. The room temperature conductivity, thermopower and thermal conductivity of Yb5Al2Sb6/0.5Ge were 1100 S/cm, 20μ V/K, and 3.8 W/m K, respectively.
UR - http://www.scopus.com/inward/record.url?scp=54749111519&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=54749111519&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:54749111519
VL - 1044
SP - 199
EP - 204
BT - Materials Research Society Symposium Proceedings
ER -