Zn(tbip) (H2tbip= 5-tert-butyl isophthalic acid)

A highly stable guest-free microporous metal organic framework with unique gas separation capability

Long Pan, Brett Parker, Xiaoying Huang, David H. Olson, JeongYong Lee, Jing Li

Research output: Contribution to journalArticle

421 Citations (Scopus)

Abstract

A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 Å. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm3 at 77 K and 1 atm).

Original languageEnglish
Pages (from-to)4180-4181
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number13
DOIs
Publication statusPublished - Apr 5 2006

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Methanol
Hydrogen
Ethers
Thermodynamic stability
Hot Temperature
Gases
Metals
Acids
Water
isophthalate
dimethyl ether

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Zn(tbip) (H2tbip= 5-tert-butyl isophthalic acid) : A highly stable guest-free microporous metal organic framework with unique gas separation capability. / Pan, Long; Parker, Brett; Huang, Xiaoying; Olson, David H.; Lee, JeongYong; Li, Jing.

In: Journal of the American Chemical Society, Vol. 128, No. 13, 05.04.2006, p. 4180-4181.

Research output: Contribution to journalArticle

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